Temperature Dependence of the Lattice Vibrations of Triglycine Sulfate
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概要
- 論文の詳細を見る
Far infrared spectra from 400 to 30 cm<SUP>−1</SUP> of triglycine sulfate and its deuterated analogue were measured and the bands due to the librational modes of glycine molecules were identified. Polarized Raman spectra below 300 cm<SUP>−1</SUP> of triglycine sulfate single crystals were measured and the symmetry species of the observed lattice vibrations were determined. Temperature dependence of the lattice vibrations was examined. Significant changes were detected in both infrared and Raman spectra on crossing the Curie temperature, indicating a flipping motion of glycine I in the paraelectric phase and suggesting the ferroelectric transition in triglycine sulfate to be of an order-disorder type.
- 公益社団法人 日本化学会の論文
著者
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Kaneko Norio
Department Of Chemistry And Material Engineering Faculty Of Engineering Shinshu University
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Takahashi Hiroaki
Department Of Biochemistry And Molecular Biology Graduate School Of Science And Engineering Saitama
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Higasi Keniti
Department of Chemistry, School of Science and Engineering, Waseda University
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