The Crystal Structure of Cupric Complex with Succinimide I. Cesium Tetrakis(succinimidato)copper(II) Dihydrate

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概要

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• The crystal structure of cesium tetrakis(succinimidato) copper(II) dihydrate, Cs<SUB>2</SUB>(Cu(sucim)<SUB>4</SUB>)·2H<SUB>2</SUB>O, has been determined by means of X-ray analysis. The crystals are violet rhombic plates. Dimensions of the triclinic unit cell are <I>a</I>=9.19, <I>b</I>=15.32, <I>c</I>=8.39 Å, α=88.7°, β=92.0°, γ=93.8°, and <I>z</I>=2. The space group is <I>C</I>\bar1. The structure has been determined by the Patterson synthesis, a series of Fourier syntheses and the least-squares method. The coordination around the copper atom is a square planar. Two independent cesium ions have a quite different environment. Complex anions, (Cu(sucim)<SUB>4</SUB>)<SUP>2−</SUP>, are linked with each other through the hydrogen bonds between water and carboxyl oxygen atoms.

• 公益社団法人 日本化学会の論文

著者

• Tsukihara Tomitake

  Faculty Of Engineering Tottori University

• KATSUBE Yukiteru

  Faculty of Engineering, Tottori University

• Fujimori Kumiko

  Faculty of Engineering, Tottori University

• Ito Toshiaki

  Faculty of Engineering, Tottori University

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