The Crystal and Molecular Structure of Bis(L-prolinamidato)-nickel(II) Dihydrate

スポンサーリンク

概要

• 論文の詳細を見る

• The crystal structure of bis(L-prolinamidato)nickel(II) dihydrate has been determined by three dimensional X-ray analysis. The crystals are vermilion needles and belong to the space group <I>P</I>2<SUB>1</SUB>. The unit cell has dimensions <I>a</I>=10.915, <I>b</I>=7.319, <I>c</I>=9.445 Å, β=112.6° and contains two structure units. The structure has been solved using Patterson synthesis, minimum function and Fourier synthesis and refined by diagonal and blockdiagonal least-squares methods on 1115 independent reflections. The final <I>R</I> value was 0.054. The nickel atom exhibits square planar coordination. Two proline-amide molecules are approximately related to each other by a two fold axis and these two ligand molecules coordinate to the central nickel atom in <I>trans</I> form. The oxygen atom of water does not coordinate to the nickel atom.

• 公益社団法人 日本化学会の論文

著者

• Tsukihara Tomitake

  Faculty Of Engineering Tottori University

• KATSUBE Yukiteru

  Faculty of Engineering, Tottori University

• Fujimori Kumiko

  Faculty of Engineering, Tottori University

• Ishimura Yoshihisa

  Faculty of Engineering, Tottori University

関連論文

• Metabolism of Paeoniflorin and Related Compounds by Human Intestinal Bacteria. II. : Structures of 7S- and 7R-Paeonimetabolines I and II Formed by Bacteroides fragilis and Lactobacillus brevis(Pharmacognosy,Chemical)
• Ordered Structure of the Crystallized Bovine 20S Proteasome
• Structure Analysis of p-Bromobenzoate of Sterigmatocystin by X-ray Diffraction Method
• The Crystal and Molecular Structure of Emericellin, A Metabolite of Aspergillus nidulans
• A Structure Analysis of a Bromo Derivative of Parasiticolide A by the X-Ray Diffraction Method
• The Crystal and Molecular Structure of Versicolorin C, A Metabolite of Aspergillus versicolor
• The Crystal and Molecular Structure of the p-Bromobenzoate of Sterigmatocystin
• Structure of Aszonapyrone A Monomethyl Ether-1, a Derivative of Aszonapyrone A, Produced by Aspergillus zonatus
• Absolute configurations of asperlin, a metabolite of Aspergillus nidulans, and its related compounds.
• Molecular structures of adducts of benzoyl isothiocyanate and hydrazones determined by the X-ray diffraction method.
• A structure analysis of a bromoacetate of hydroxypiperenone by the X-ray diffraction method.
• The Crystal Structure of the Cupric Complex with Succinimide. II. Potassium Tetrakis(succinimidato)copper(II) Hexahydrate and Lithium Tetrakis(succinimidato)copper(II) Monohydrate
• The Crystal Structure of Cupric Complex with Succinimide I. Cesium Tetrakis(succinimidato)copper(II) Dihydrate
• The Crystal Structure of o-Nitrobenzamide
• The crystal and molecular structures of 6-deoxyversicolorin A and versicolorin A, metabolites from Aspergillus versicolor.
• The crystal structures of sterigmatocystin and O-methylsterigmatocystin, metabolites of the genus Aspergillus.
• The Crystal and Molecular Structure of Sterigmatin, A Metabolite of Aspergillus versicolor
• Determination of absolute configuration of epishamixanthone, a metabolite of Aspergillus rugulosus, by anomalous scattering of light atoms.
• The Crystal and Molecular Structure of Bis(L-prolinamidato)-nickel(II) Dihydrate

もっと見る 閉じる

スポンサーリンク