The Crystal Structure of the Cupric Complex with Succinimide. II. Potassium Tetrakis(succinimidato)copper(II) Hexahydrate and Lithium Tetrakis(succinimidato)copper(II) Monohydrate

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概要

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• As part of a program for the study of the crystal structure of copper(II)-complex with succinimide, the crystal structures of potassium tetrakis(succinimidato) copper(II) hexahydrate and lithium tetrakis(succinimidato) copper(II) monohydrate have been determined by means of X-ray analysis. In the potassium-salt, the copper atom has a square planar coordination and the potassium ion has a trigonal prismatic environment formed by six oxygen atoms. In the lithium-salt, the copper atom has a flattened tetrahedral coordination, and each lithiun ion is tetrahedrally surrounded by four oxygen atoms. The conformational difference between the complex anion of the potassium-salt and that of the lithium-salt seems to result from the different sizes of the alkali-metal ions.

• 公益社団法人 日本化学会の論文

著者

• Tsukihara Tomitake

  Faculty Of Engineering Tottori University

• KATSUBE Yukiteru

  Faculty of Engineering, Tottori University

• Fujimori Kumiko

  Faculty of Engineering, Tottori University

• Kawashima Kiyoshi

  Faculty of Engineering, Tottori University

• Kan-Nan Yoshiaki

  Faculty of Engineering, Tottori University

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