An ENDOR Study of the Relaxation Behavior of the Nuclei in Several Semiquinone Anion Radicals
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概要
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The ENDOR intensities of several semiquinone anion radicals were measured at various temperatures. The optimum temperature for the ENDOR intensity of protons in a radical was interpreted on the basis of their characteristic ways of relaxation. The electron nuclear dipolar (END) mechanism could be applied very well in most cases. However, in the case of protons whose END terms are very small this interaction might not explain the optimum temperature. Possible substitute mechanisms were discussed.
- 公益社団法人 日本化学会の論文
著者
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Kuwata Keiji
Department Of Chemistry Faculty Of Science Osaka University
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KUWATA Keiji
Department of Chemistry, Faculty of Science, Osaka University
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Kotake Yashige
Department of Chemistry Faculty of Science, Osaka University
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