ENDOR relaxation study of the effects of intramolecular cation migration on the ion-pair system.
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概要
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The ENDOR spectra of the ion-pair system of the 2,5-di-<I>t</I>-butyl-<I>p</I>-benzoquinone anion and the alkali metal cation in 1,2-dimethoxyethane were observed. The influence of the intramolecular cation migration on both the linewidth and the intensity of the ENDOR spectra was experimentally examined. The results obtained were discussed theoretically using the Kaplan-Alexander formula. The intramolecular exchange due to the cation migration was shown to be effective in ENDOR.
- 公益社団法人 日本化学会の論文
著者
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Kuwata Keiji
Department Of Chemistry Faculty Of Science Osaka University
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Okazaki Masaharu
Department of Chemistry, Faculty of Science, Osaka University
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