ESR study of SeO2- radical in an irradiated single crystal of triglycine selenate in the vicinity of phase transition temperature.

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概要

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• Detailed observations of the angular dependence of ESR spectra of SeO<SUB>2</SUB><SUP>−</SUP> radicals formed by X-ray irradiation of a single crystal of ferroelectric triglycine selenate were carried out. Two kinds of SeO<SUB>2</SUB><SUP>−</SUP> radicals were produced due to the difference in manner of selenium-oxygen bond scission. In spite of the difference in stability of radicals in TGSe and those in TGS, the behavior of SeO<SUB>2</SUB><SUP>−</SUP> radicals in the phase transition region is in line with that expected from the result of X-ray diffraction study of TGS.

著者

• Kotake Yashige

  Department of Chemistry Faculty of Science, Osaka University

関連論文

• ESR study of SeO2- radical in an irradiated single crystal of triglycine selenate in the vicinity of phase transition temperature.
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