Copper(II) Complexes of L-Histidylglycine and L-Histidylglycylglycine in Aqueous Solution
スポンサーリンク
概要
- 論文の詳細を見る
Equilibrium constants were determined in the complex formations of L-histidylgylcine (HG) and L-histidylglycylglycine (HGG) with copper(II) ion in aqueous solution by potentiometric titration, and the structures of the complexes were discussed based on the observations in the titration and infrared and electronic absorption spectra. In the acid region, a cationic chelate, in which copper(II) binds to nitrogen atoms of amino and imidazole groups, is formed. In the neutral region, deprotonation of the peptide amide group occurs to form a dimer, in which four coordination positions of copper(II) are occupied by nitrogen atoms of deprotonated amide and amino groups and an oxygen atom of carboxyl or carbonyl group in one molecule and a nitrogen atom of imidazole group of another molecule. In HGG–Cu(II) system, the dimer is decomposed in the alkaline region with further deprotonation of the second peptide amide group to form an anionic chelate as in the case of the glycylglycylglycine–Cu(II) complex.
- 公益社団法人 日本化学会の論文
著者
-
Aiba Hiroji
Faculty Of Pharmaceutical Science Suzuka University Of Medical Science
-
Tanaka Hisashi
Faculty Of Engineering University Of Miyazaki
-
YOKOYAMA AKIRA
Faculty of Agriculture, Nagoya University
関連論文
- Initial clinical experiences with dopamine D_2 receptor imaging by means of 2'-iodospiperone and single-photon emission computed tomography
- Clinical application of ^Zn/^Cu positron generator: Perfusion and plasma pool images in normal subjects
- Canine SPECT studies for cerebral amino acid transport by means of ^I-3-iodo-α-methyl-L-tyrosine and preliminary kinetic analysis
- 1P259 大腸菌における光誘導型タンパク質発現制御系の確立に向けて(光生物-視覚・光受容,第48回日本生物物理学会年会)
- Synthesis and Characterization of Radioiodinated (S)-5-Iodonicotine : A New Ligand for Potential Imaging of Brain Nicotinic Cholinergic Receptors by Single Photon Emission Computed Tomography
- Low-Voltage, Wide-Common-Mode-Range and High-CMRR CMOS OTA
- Design of CMOS OTAs for Low-Voltage and Low-Power Application
- A CATALYTIC ACTIVITY OF ION-EXCHANGE RESINS MODIFIED WITH METAL-PORPHINES IN OXIDATIVE REACTION OF ASCORBIC ACID
- RESONANCE RAMAN SPECTRA OF ION-EXCHANGE RESINS MODIFIED WITH METALLOPOR-PHYRINS HAVING A CATALYTIC OXIDATIVE FUNCTION FOR URIC ACID AND GLUTATHIONE
- PEROXIDASE-LIKE ACTIVITY OF ANION-EXCHANGE RESINS MODIFIED WITH METALLO-PORPHYRINS
- Preconcentration of Selenium by the Use of an Anion-Exchange Resin Loaded with Bismuthiol Derivatives (Proceedings of the 14th Symposium on Environmental Pollutants and Toxicology)
- THE ION-EXCHANGE RESINS MODIFIED WITH METALLO-PORPHYRINS AND THEIR CATALYTIC ACTIVITY IN THE OXIDATION OF URIC ACID
- A NONLINEAR MULTIPLE REGERSSION PROGRAM, MULTI2 (BAYES), BASED ON BAYESIAN ALGORITHM FOR MICROCOMPUTERS
- Low-Voltage, Low-Distortion and Rail-to-Rail CMOS Sample and Hold Circuit(Nonlinear Theory and its Applications)
- Separation and Determination of Fluoride Ion by Using Ion Exchange Resin Loaded with Alizarin Fluorine Blue(Analytical,Chemical)
- A NEW VERSION OF MULTI (ELS) FOR EXTENDED NONLINEAR LEAST SQUARES
- A Numerical Method for Compressible Viscous Flow with a Multi Grid Algorithm
- Changes in Body Weight, Milk Production, Food and Water Consumptions and Vaginal Smears in Rats during Prolonged Lactation
- IRON COMPLEXES OF BLEOMYCIN AND DEGLYCO-BLEOMYCIN : SPECTROSCOPIC PROPERTIES AND NUCLEOTIDE SEQUENCE SPECIFICITY IN DNA CLEAVAGES
- Specific Binding of Prolactin to the Mammary Gland and Lactose Synthesis in Pregnant Rats After Removal of Ovaries or Ovaries and Adrenals
- Public Choice on Migrant Workers (ESSAYS IN COMMEMORASTION OF THE SEVENTIETH BIRTHDAY OF PROFESSOR TAKUO TANAKA)
- Effect of Intrahypothalamic Implantation of Dibenamine on Milk-Ejection Reflex in Lactating Rats
- Rapid Decrease and Restoration of Acetylcholinesterase Activity in the Hypothalamus of the Rat in Response to Suckling Stimulus
- Catalase-like activity of anion-exchange resin modified with metalloporphyrin in the oxidation of methyl alcohol and its application to the determination of hydrogen peroxide.
- The complexing of indium(III) by cysteine: evidence for sulfurbridged and protonated complexes.
- Copper(II) Complexes of Histidine and Its Related Compounds in Aqueous Solutions
- Copper(II) Complexes of L-Histidylglycine and L-Histidylglycylglycine in Aqueous Solution
- Complexation between copper(II) ion and large excess histidine in aqueous solution.