Electrical Behavior of Alkali Metal Cation–TCNQ Anion Radical Simple Salts under Very High Pressures.
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概要
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The electrical resistance of alkali metal cation–TCNQ anion radical simple salts was measured over the wide pressure range from 0 to 500 kbar at room temperature. The least resistivities for Group A (Li–, Na–, K–, and Rb(I)–TCNQ) are about 0.2–3 Ωcm, while those for Group B (Rb(II)– and Cs–TCNQ) are about 0.06–0.1 Ωcm. The possibility of insulator-metal transition at high pressures is discussed. Above 140–175 kbar the electrical resistance of simple TCNQ salts increases with an increase in the pressure and drifts upward with the time. The solid-phase reaction is observed under very high pressures.
- 公益社団法人 日本化学会の論文
著者
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Shirotani Ichimin
The Institute For Solid State Physics The University Of Tokyo
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Onodera Akifumi
Department Of Material Physics Faculty Of Engineering Science Osaka University
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Sakai Nobuko
The Institute for Solid State Physics, The University of Tokyo
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