Proton Magnetic Resonance Spectra of L- or D-Aspartato (L-2,4-diaminobutyrato)cobalt(III) Complexes
スポンサーリンク
概要
- 論文の詳細を見る
Three diastereomeric isomers of the L-aspartato(L-2,4-diaminobutyrato)cobalt(III) and two of the D-aspartato (L-2,4-diaminobutyrato)cobalt(III), Co(N)<SUB>3</SUB>(O)<SUB>3</SUB> type were prepared and isolated. The isomers were characterized by their electronic absorption and proton magnetic resonance spectra. Their PMR spectra indicate that the carbon proton adjacent to the coordinated N atom resonates at a higher magnetic field when O atom occupies the site <I>trans</I> to the N atom than when N atom occupies the same place.
- 公益社団法人 日本化学会の論文
著者
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Yoshikawa Sadao
Department Of Applied Chemistry Faculty Of Science And Technology Keio University
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Watabe Masatoshi
General Education Department Kogakuin University
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Onuki Kenji
Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo
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