15N NMR spectra of cobalt(III) complexes containing 15NO2-.

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概要

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• The nitrogen-15 nuclear magnetic resonance spectra of the cobalt(III) complexes containing <SUP>15</SUP>NO<SUB>2</SUB><SUP>−</SUP> were first measured; the coordination chemical shifts, Δδ (=δ<SUB>complex</SUB>–δ<SUB>free</SUB>), were found to be from 135.0 to 161.5 ppm. The relationship between Δδ and the geometrical configuration was discussed in terms of the paramagnetic anisotropy of the cobalt(III) ion.

• 公益社団法人 日本化学会の論文

著者

• Watabe Masatoshi

  General Education Department Kogakuin University

• Odaka Yoshio

  General Education Department, Kogakuin University

• Yamasaki Akira

  General Education Department, Kogakuin University

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