Preparation and isomerization of three isomers of L-histidinatoiminodiacetatocobalt(III) complex.
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概要
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Three isomers of L-histidinatoiminodiacetatocobalt(III) complex have been prepared and characterized on the basis of their absorption, circular dichroism and proton magnetic resonance spectra. These isomers isomerized mutually in water at 80 °C. The equilibrium mole fractions of these isomers in water were found for <I>cisN</I>, <I>transN</I> and <I>fac</I> to be 0.91, 0.04, and 0.05, respectively.
- 公益社団法人 日本化学会の論文
著者
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Yoshikawa Sadao
Department Of Applied Chemistry Faculty Of Science And Technology Keio University
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Watabe Masatoshi
General Education Department Kogakuin University
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Watabe Masatoshi
General Education Department of Kogakuin University
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Zama Masayuki
General Education Department of Kogakuin University
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