Preparation of sodium bis(L-aspartato)rhodate(III).

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概要

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• Bis(L-aspartato) rhodate(III) complex was prepared and separated into three isomers, and their absorption, CD curves and <SUP>1</SUP>H NMR spectra are presented. The geometrical configurations of three isomers are assigned mainly on the basis of the spectral analogy between this complex and the [Co(L-asp)<SUB>2</SUB>]<SUP>−</SUP> complex.

• 公益社団法人 日本化学会の論文

著者

• Watabe Masatoshi

  General Education Department Kogakuin University

• Odaka Yoshio

  General Education Department, Kogakuin University

• Furihata Kenji

  General Education Department, Kogakuin University

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• Preparation of (L-cysteinato)(L- or D-histidinato)chromium(III) complex.
• Preparation and isomerization of isomers of the L- or D-aspartato(L-histidinato)cobalt(III) complex.
• Preparation of sodium bis(L-aspartato)rhodate(III).
• Proton Magnetic Resonance Spectra of L- or D-Aspartato (L-2,4-diaminobutyrato)cobalt(III) Complexes
• Preparation and isomerization of three isomers of L-histidinatoiminodiacetatocobalt(III) complex.
• Isomerization of the (D-aspartato)(L-2,4-diaminobutyrato)cobalt(III) complex.

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