Studies on O.RAR.N acyl migration in O-acyl-2-deoxystreptamines.
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概要
- 論文の詳細を見る
Preparations of mono-<I>N</I>-protected 2-deoxystreptamines (racemates of <B>5</B>, <B>8</B>, <B>9</B>, <B>10</B>, <B>11</B>, <B>12</B>) from 4(and 6)-<I>O</I>-acyl-1,3-di-<I>N</I>-benzyloxycarbonyl-2-deoxystreptamines by O→N acyl migration were described. O→N Acyl migration of 2-deoxy-tri-<I>O</I>-ethoxycarbonylstreptamine (<B>15</B>) led to several protected derivatives (racemates of <B>16</B>, <B>17</B>, <B>18</B>) which also should serve for the preparation of glycosides and other derivatives of 2-deoxystreptamine.
- 公益社団法人 日本化学会の論文
著者
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Tsuchiya Tsutomu
Institute of Bioorganic Chemistry
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Umezawa Sumio
Institute of Bioorganic Chemistry
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Nishimura Yoshio
Institute of Bioorganic Chemistry
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Kurisu Takao
Department of Applied Chemistry, Faculty of Engineering Keio University
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Yamashita Michio
Department of Applied Chemistry, Faculty of Engineering Keio University
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Miyake Toshiaki
Department of Applied Chemistry, Faculty of Engineering Keio University
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