The effect of pressure on the dissociation of weak acids in aqueous buffers.
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概要
- 論文の詳細を見る
The effect of pressure on the dissociation of boric acid, imidazole HCl, and H<SUB>2</SUB>PO<SUB>4</SUB><SUP>−</SUP> in aqueous buffers has been investigated up to 6 kbars, using as optical indicators <I>p</I>-nitrophenol and Cresol Red. The limiting volume change on ionization at atmospheric pressure (Δ\bar<I>V</I>°) and the compressibility change (Δ\barκ°) for these weak acids were obtained. The values of Δ\bar<I>V</I>° (cm<SUP>3</SUP> mol<SUP>−1</SUP>) and Δ\barκ° (cm<SUP>3</SUP> mol<SUP>−1</SUP> kbar<SUP>−1</SUP>) are −10.1 and −0.4 for Cresol Red, −30.2 and −4.3 for boric acid, and −2.4 and −0.6 for imidazole H<SUP>+</SUP>.
- 公益社団法人 日本化学会の論文
著者
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Shirotani Ichimin
Institute For Solid State Physics University Of Tokyo
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MINOMURA Shigeru
Institute for Solid State Physics, The University of Tokyo
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Tsuda Motoyuki
Department Of Life Science Faculty Of Science Himeui Institute Of Technology
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Terayama Yoshio
Department Of Physics Sapporo Medical College
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Minomura Shigeru
Institute For Solid State Physics The University Of Tokyo
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TSUDA Motoyuki
Department of Physics, Sapporo Medical College
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Tsuda Motoyuki
Department of Chemistry, Faculty of Science, Hokkaido University
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