The reactions of the dimers of hexalluoropropene with O-nucleophiles.
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The reactions of the dimers of hexafluoropropene with alcohols and phenol in the presence of triethylamine, and with sodium alkoxides and phenolate were carried out. Of the two dimers, perfluoro-2-methyl-2-pentene (Dimer <B>2</B>) was much more reactive than perfluoro-4-methyl-2-pentene (Dimer <B>1</B>). While the dimer <B>2</B> and <I>O</I>-nucleophiles gave various addition and substitution products very easily, the dimer <B>1</B> reacted only with sodium alkoxides to give trialkoxylated products.
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- The reactions of the dimers of hexalluoropropene with O-nucleophiles.