Formation of dialkyl .ALPHA.-siloxybenzylphosphonate via 1,2-anionic rearrangement of a silyl group.
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概要
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The reactions of silyl phenyl ketones with trialkyl phosphites and dialkyl sodiophosphonates gave dialkyl α-siloxybenzylphosphonates in good yields. The mechanism involves the migration of a silyl group from carbon to anionic oxygen. No deoxygenation of silyl ketone with trialkyl phosphite was observed.
- 公益社団法人 日本化学会の論文
著者
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Sekiguchi Akira
Department Of Chemistry And Organosilicon Research Laboratory
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Ando Wataru
Department of Chemistry Radiation Center of Osaka Prefecture
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Sekiguchi Akira
Department of Chemistry, The University of Tsukuba
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Ikeno Masayuki
Department of Chemistry, The University of Tsukuba
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