A Novel Tetralithium Salt of a Tetraanion and a Dilithium Salt of a Dianion, formed by the Reduction of the Tetrasilylethylene Moiety. Synthesis, Characterization, and Observation of an Si-H・・・Li^+ Interaction
スポンサーリンク
概要
- 論文の詳細を見る
- Chemical Society of Japanの論文
- 2000-07-15
著者
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MATSUO Tsukasa
Department of Chemistry, Faculty of Science, Tohoku University
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SEKIGUCHI Akira
Department of Chemistry, Faculty of Science, Tohoku University
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Matsuo Tsukasa
Department Of Chemistry University Of Tsukuba
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WATANABE Hidetoshi
Department of Chemistry, University of Tsukuba
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Sekiguchi Akira
Department Of Chemistry And Organosilicon Research Laboratory
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Sekiguchi Akira
Dep. Of Chemistry Graduate School Of Pure And Applied Sciences Univ. Of Tsukuba
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Watanabe Hidetoshi
Department Of Chemistry University Of Tsukuba
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- The Chemistry of Disilyne with a Genuine Si-Si Triple Bond : Synthesis, Structure, and Reactivity
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- Photochemical Generation of Halo(silyl)silylene : Spectroscopic Observation and Reactivity
- Photochemical Generation of Chlorine-substituted Digermenes and Their Rearrangement to Germylgermylenes
- Photoisomerization of Persilyl-Substituted Silacyclopropene: Formation of Stable Persilyl-Substituted 1-Silaallene, and Its Reactivity
- Reaction of 1-Disilagermirene with Benzaldehyde: An Unexpected Combination of Cycloaddition and Insertion Pathways
- Synthesis and Structure of Cyclotrigermenium Salt of the Tetrakis {3,5-bis (tri-fluoromethyl) phenyl} borate Anion. A Stable Free Germyl Cation in the Condensed Phase
- Formation and Structure of Protonated Tetrasilatetrahedrane-monooxide, (tert-Bu_3Si)_4Si_4OH^+
- Syntheses of Dialkali Metal Complexes of Tetrakis(dimethylsilyl)ethylene : [(HMe_2Si)_2C=C(SiMe_2H)_2]^[M^+(ligande)_n]_ Evidence for siH-Alkali Metal Agostic Interactions
- Highly Twisted Ethylene Dianion Dilithium Stabilized by Phenyl and Silyl Groups
- Dianion Dialkali Metals of 2,2',5,5'-Tetrasilabicyclopentylidene. Synthesis and Crystal Structures
- Structure of 1,2-Dilithio[tetrakis(trimethylsilyl)]ethane in Solution. Observation of Lithium-Bridged Structures and Unexpected Anionic Rearrangement
- Synthesis and Reduction of Silyl-Substituted [5]Radialene. Characterization and Structure of a[5]Radialene Tetraanion with a Ten-Center, Fourteen-Electron π-sYSTEM
- Silyl-Substituted Dilithium Salt of Fulvene Dianion with 6 Center/8 Electron π-System : Synthesis and Characterization
- Isolation and Molecular Structure of Persilylated [5] Radialene : Intramolecular Cyclization of a Macrocyclic Pentayne with Mn (CO)_3 (Me-Cp)
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- Crystal Structures of Unsolvated Lithiosilanes with Si-Si Bonds
- Lithiosilanes with Si-Si Bonds : Synthesis and ^6Li, ^7Li, and ^Si NMR Studies
- Cyclobutadiene Dianion
- Synthesis of Cyclotetragermanes of the Type of [R(Ph)Ge]_4 and Conversion to [R(Cl)Ge]_4. The First Functionalized Cyclotetragemanes
- An Isolable Boryl-substituted Disilene from the Reaction of an sp^2-type Silyl Anion with Haloboranes : Synthesis and Characterization
- Disilenyl Anions Derived from Reduction of Tetrakis(di-tert-butylmethylsilyl)disilene with Metal Naphthalenide through a Disilene Dianion Intermediate : Synthesis and Characterization
- Heteronuclear Double Bonds E=E' (E=Heavy Group 14 Element, E'=Group 13-16 Element)
- Silylcarbene-to-Silene Rearrangement : Stable 1,2-Dihydrosilenes in Solution via the Silylcarbene Route
- Making Stable Radicals of Heavy Elements of Groups 14 and 13 : The Might of Silyl Substitution
- Two-coordinate Group 13 Element (Al, Ga) Centered Cations Formed by Silyl Group Migration : Synthesis and Characterization
- Molecular Structure of Phenyl[tris(trimethylsilyl)]ethylene Dilithimu Complex. An Orthogonal Dianion
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- Anion Chemistry of Silyl-Substituted π-Electron Systems Based on Four-and Five-Membered Rings
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- Some New Applications of Neutron Slowing Down Time Spectrometry
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