The Chemistry of Disilyne with a Genuine Si-Si Triple Bond : Synthesis, Structure, and Reactivity

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概要

• 論文の詳細を見る
• Chemical Society of Japanの論文
• 2006-06-15

著者

• SEKIGUCHI Akira

  Department of Chemistry, Faculty of Science, Tohoku University

• ICHINOHE Masaaki

  Department of Chemistry, Graduate School of Science, Tohoku University

• 関口 章

  Department Of Chemistry Graduate School Of Pure And Applied Sciences University Of Tsukuba

• Sekiguchi Akira

  Department Of Chemistry Graduate School Of Pure And Applied Sciences University Of Tsukuba

• Ichinohe Masaaki

  Department Of Chemistry Graduate School Of Pure And Applied Sciences University Of Tsukuba

• Masaaki Ichinohe

  Department Of Chemistry Graduate School Of Pure And Applied Sciences University Of Tsukuba

• KINJO Rei

  Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba

• Kinjo Rei

  Department Of Chemistry Graduate School Of Pure And Applied Sciences University Of Tsukuba

• Sekiguchi Akira

  Department Of Chemistry And Organosilicon Research Laboratory

• Sekiguchi Akira

  Dep. Of Chemistry Graduate School Of Pure And Applied Sciences Univ. Of Tsukuba

関連論文

• 官能性シクロテトラゲルマンおよびはしご形ポリゲルマンの合成と構造
• Intramolecular Oligomerization of Disilalkylene{-Me_2Si(CH_2)_nSiMe_2-}Bridged Cyclic Triacetylenes^1
• Tetraanion Tetralithium with 8 Center/12 Electron π-System Stabilized by Silyl Groups. Synthesis and Characterization
• Synthesis and Structure of a Stable Cyclic Dialkylgermylene
• Synthesis and Reduction of Octasilyl[4]radialene. Structure and Dynamic Study of [4]Radialene Dianion with Eight-Center Ten-Electron π-System
• Persilylated Dimethylenecyclobutene Dianion Dilithium as the First 6C-8π Allyl Anion System
• Persistent Tris (t-butyldimethylsilyl) silyl Radical and Its New Generation Methods
• 1,3-Digerma-2-gallata- and -indataallenic Anions : The First Compounds with Ge=Ga or Ge=In Double Bonds
• The Chemistry of Disilyne with a Genuine Si-Si Triple Bond : Synthesis, Structure, and Reactivity
• 1,2,5,6-Tetrasilabenzobenzvalene : A Valence Isomer of 1,2,3,4-Tetrasilanaphthalene
• Reaction of Dilithiosilane R_2SiLi_2 and Dilithiogermane R_2GeLi_2 (R = SiMe^tBu_2) with MesBCl_2 (Mes = 2, 4, 6-trimethylphenyl) : Evidence for the Formation of Silaborene R_2Si=BMes and Germaborene R_2Ge=BMes
• Photochemical Generation of Halo(silyl)silylene : Spectroscopic Observation and Reactivity
• Photochemical Generation of Chlorine-substituted Digermenes and Their Rearrangement to Germylgermylenes
• Photoisomerization of Persilyl-Substituted Silacyclopropene: Formation of Stable Persilyl-Substituted 1-Silaallene, and Its Reactivity
• Reaction of 1-Disilagermirene with Benzaldehyde: An Unexpected Combination of Cycloaddition and Insertion Pathways
• Synthesis and Structure of Cyclotrigermenium Salt of the Tetrakis {3,5-bis (tri-fluoromethyl) phenyl} borate Anion. A Stable Free Germyl Cation in the Condensed Phase
• Formation and Structure of Protonated Tetrasilatetrahedrane-monooxide, (tert-Bu_3Si)_4Si_4OH^+
• Syntheses of Dialkali Metal Complexes of Tetrakis(dimethylsilyl)ethylene : [(HMe_2Si)_2C=C(SiMe_2H)_2]^[M^+(ligande)_n]_ Evidence for siH-Alkali Metal Agostic Interactions
• Synthesis and Structure of a Series of Oligo[1, 1-(2, 3, 4, 5-tetramethylsilole)]s
• Highly Twisted Ethylene Dianion Dilithium Stabilized by Phenyl and Silyl Groups
• Dianion Dialkali Metals of 2,2',5,5'-Tetrasilabicyclopentylidene. Synthesis and Crystal Structures
• Structure of 1,2-Dilithio[tetrakis(trimethylsilyl)]ethane in Solution. Observation of Lithium-Bridged Structures and Unexpected Anionic Rearrangement
• Synthesis and Reduction of Silyl-Substituted [5]Radialene. Characterization and Structure of a[5]Radialene Tetraanion with a Ten-Center, Fourteen-Electron π-sYSTEM
• Silyl-Substituted Dilithium Salt of Fulvene Dianion with 6 Center/8 Electron π-System : Synthesis and Characterization
• Isolation and Molecular Structure of Persilylated [5] Radialene : Intramolecular Cyclization of a Macrocyclic Pentayne with Mn (CO)_3 (Me-Cp)
• A Novel Tetralithium Salt of a Tetraanion and a Dilithium Salt of a Dianion, formed by the Reduction of the Tetrasilylethylene Moiety. Synthesis, Characterization, and Observation of an Si-H・・・Li^+ Interaction
• Reaction of Bis[bis(trimethylsilyl)methyl]germylene with Tris(4-tert-butylphenyl)methylium Ion : Formation of a Unique Germyl Cation Weakly σ-Coordinated to Aromatic Group
• Crystal Structures of Unsolvated Lithiosilanes with Si-Si Bonds
• Lithiosilanes with Si-Si Bonds : Synthesis and ^6Li, ^7Li, and ^Si NMR Studies
• Cyclobutadiene Dianion
• Synthesis of Cyclotetragermanes of the Type of [R(Ph)Ge]_4 and Conversion to [R(Cl)Ge]_4. The First Functionalized Cyclotetragemanes
• An Isolable Boryl-substituted Disilene from the Reaction of an sp^2-type Silyl Anion with Haloboranes : Synthesis and Characterization
• Disilenyl Anions Derived from Reduction of Tetrakis(di-tert-butylmethylsilyl)disilene with Metal Naphthalenide through a Disilene Dianion Intermediate : Synthesis and Characterization
• Heteronuclear Double Bonds E=E' (E=Heavy Group 14 Element, E'=Group 13-16 Element)
• Silylcarbene-to-Silene Rearrangement : Stable 1,2-Dihydrosilenes in Solution via the Silylcarbene Route
• Making Stable Radicals of Heavy Elements of Groups 14 and 13 : The Might of Silyl Substitution
• エキゾチックな有機ケイ素化合物 (広がる有機ケイ素化学の世界)
• 14族元素多環式化合物の化学 (1990年の化学-12完-)
• Two-coordinate Group 13 Element (Al, Ga) Centered Cations Formed by Silyl Group Migration : Synthesis and Characterization
• Molecular Structure of Phenyl[tris(trimethylsilyl)]ethylene Dilithimu Complex. An Orthogonal Dianion
• シリルリチウムの最近の発展--ポリシラニルリチウムとアミノシリルリチウム (1992年の化学-11-)
• Silylium Ions Stabilized by an Si-X-Si Three-center Bond (X=Halogen or Hydrogen)
• Anion Chemistry of Silyl-Substituted π-Electron Systems Based on Four-and Five-Membered Rings
• Synthesis of ^tBu_3E^+ Nitrile Complexes by Oxidative Cleavage of ^tBu_3E-E^tBu_3(E=Si, Ge, Sn)
• Silylium Ion to silylium Ion Rearrangement Caused by 1, 3-Methyl Migration
• Unexpected Hydrolithiation of M=M'Double Bond (M, M'=Si, Ge) with ^tBuLi
• Thia- and Selenasilaboriranes and 1,3,2,4-Dioxasilaboretane from a Stable Silaborene
• Synthesis and Molecular Structure of a Dilithium Salt of the cis-Diphenylcyclobutadiene Dianion
• Some New Applications of Neutron Slowing Down Time Spectrometry
• Formation of indan and 2,3-dihydrobenzofuran via intramolecular insertion of phenylcarbene.
• Synthesis of cyclic silyl diazo compounds.
• Formation of dialkyl .ALPHA.-siloxybenzylphosphonate via 1,2-anionic rearrangement of a silyl group.

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