The preparation and some properties of 3-substituted 2,4-pentanedionato metal(II, III) complexes.
スポンサーリンク
概要
- 論文の詳細を見る
In the substitution reactions of phenol, benzenethiol, and their sodium salts on the chelate ring of 3-bromo-2,4-pentanedionato metal complexes (metal=iron(III), aluminium(III), and beryllium(II)), benzenethiol was found to be substituted for bromine, while phenol was not substituted under the same conditions. In the case of sodium salts, both sodium phenoxide and benzenethiolate gave substituted products. The UV and PMR data of tris(3-substituted 2,4-pentanedionato)aluminium(III) complexes gave some information on the substituted groups.
- 公益社団法人 日本化学会の論文
著者
-
Yamamoto Yasuo
Department Of Chemistry College Of Science Rikkyo University
-
Kasuga Kuninobu
Department Of Material Science Interdisciplinary Faculty Of Science And Engineering Shimane Universi
-
Yamamoto Yasuo
Department of Chemistry, Faculty of Literature and Science, Shimane University
-
Anami Masao
Department of Chemistry, Faculty of Literature and Science, Shimane University
-
Kasuga Kuninobu
Department of Chemistry, Faculty of Literature and Science, Shimane University
関連論文
- Monomeric 10-Sb-5 Pentacoordinate Organoantimony Monohalides and Their Permutational Behavior
- Synthesis, Structure, and Reactions of 10-Sn-5 Organotin Ate Complexes
- Polymer Complexes of Rhodium(II) Trifluoroacetamidate with Pyrazine, 4,4'-Bipyridine, and 1,4-Diazabicy-clo[2.2.2]octane
- Adduct Polymers and Dimers of Rhodium(II) Pivalate with Pyrazine, 4, 4'-Bipyridine, 1, 4-Diazabicyclo[2. 2. 2]octane, Triethylamine, and Pyridine
- Synthesis, Structure, and Reactions of a 10-Sb-4 Type Antimony Ate Complex
- Cycloaddition of Carbon Dioxide to 1,2-Epoxypropane Catalyzed by Tetra-t-butylphthalocyaninatoaluminium(III) Hydroxide
- Preparation and Electrochemical Properties of the Green Ytterbium (III) and Lutetium (III) Sandwich Complexes of Octabutoxy-Substituted Phthalocyanine
- Large Annular Purpura and Paraneoplastic Purpura in a Patient with Sjogren's Syndrome and Cervical Cancer
- Erythema Elevatum Diutinum Complicated by Rheumatoid Arthritis
- Dinuclear and Tetranuclear Copper(II) Complexes with a Ligand Bearing Phthalocyanine and Schiff-Base Coordination Sites
- Synthesis and Magnetic Properties of a Planar Binuclear Copper(II) Phthalocyanine Complex
- Preparation and Properties of Tetra- and Octa-substituted Phthalocyanines with Cationic Trimethylaniliniumyl Groups
- Polymer and "Trimer-of-Dimers" Complexes Derived from [Rh_2(form)_4] (form^-=N, N'-Di-p-tolylformamidinate anion) and 1, 4-Diisocyanobenzene
- Syntheses and Magnetic Properties of Ruthenium(II, III) Pivalate Dimers Axially Coordinated by Nitronyl Nitroxide Radicals [Ru_2(O_2CCMe_3)_4-(L)_2]BF_4 and [{Ru_2(O_2CCMe_3)_4(L)_2}{Ru_2(O_2CCMe_3)_4(H_2O)_2}]_n(BF_4)_, L=2, 4, 4, 5, 5-Pentamethyl-4,
- Photocatalytic Activity of Phthalocyaninatozinc(II) Bearing Dendritic Subsituents at α Positions in Aerated Dimethyl Sulfoxide
- Unusual Absorption Spectra Found for Some Phthalocyaninatozinc(II) Complexes Bearing Dendritic Substituents at α Positions
- Structure and Magnetic Properth of Ru(II,III) Dimer Axially Coordinated by the Niroxide Radical and Water [Ru_2(O_2CCMe_3)_4(nitph)(H_2O)]BF_4,nitph = 2-Phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide
- Structure and Magnetic Property of a Macrocyclic Tetranuclear Copper(II) Complex with Phenoxo- and Hydroxo-Bridges and Large and Small Cu-O-Cu Angles
- Structures and Magnetic Properties of Ruthenium(II, III) Pivalate Cation Dimers Axially Coordinated by Pyridyl Nitronyl Nitroxide Radicals through Their Pyridyl Nitrogen Atoms
- Phthalocyanines Obtained from Phthalonitriles with Phenyl Derivatives: A New Method for the Synthesis of the Phthalonitriles by Use of Suzuki - Coupling Reaction
- Kinetic Study on the Oxidation of Trichlorophenol Using Hydrogen Peroxide and an Iron(III) Complex of Tetrasulfonatophthalocyanine Catalyst
- Stabilized Self-Sustained Sequence Replication against Evolutionary Instability
- Structure and Some Properties of (Alkoxo)(subphthalocyaninato)boron(III)
- A New "Dimer-of-Dimers" Complex Derived from Axial Coordination of 7, 7, 8, 8-Tetracyanoquinodimethane to Ru(II, III)Cation Dimer
- Chain Compound of Mixed - Valent Ruthenium Dimers Linked by Hydrogen - Bonding between the Axially Coordinated Nitronyl Nitroxide and Water Molecules
- Chain Compounds of Molybdenum(II) Trifluoroacetate Linked by p-Quinones [Mo_2(O_2CCF_3)_4(p-quin)]_n, p-quin = 9,10-anthraquinone, 2,6-dimethyl-1,4-benzoquinone, and 1,4-naphthoquinone
- Ferromagnetic Chain Complex of Ruthenium (II, III) Pivalate with Pyridy Nitronyl Nitroxide
- Structure and Magnetic Properties of a Chain Complex with Alternating Ru(II,III) Dimer and Nitroxide Radical Arrangement [Ru_2(O_2CCMe_3)_4(nitph)]_n(BF_4)_n, nitph = 2-Phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 3-N-Oxide
- Photoreduction of Hydrogencarbonate or Ethylene Catalyzed by Trisodium Trisulfonatophthalocyaninatozincate(II)
- Preparation and Some Properties of One Structural Isomer of Tetra-Substituted Phthalocyanine; 1, 8, 15, 22-Tetrakis(pentan-3'-yloxy)phthalocyanine and Its Metal(II) Complexes^
- Chain Compounds of Rhodium(II) Trifluoroacetate Linked by p-Quinone Rh_2(O_2CCF_3)_4(p-Q)]_n, p-Q=1, 4-Benzoquinone, 1, 4-Naphthoquinone, and 2, 3-Dimethy1-1, 4-benzoquinone
- A Chain Complex of Ruthenium (II, III) Cation Dimer Linked by a Nitroxide Radical, [Ru_2 (O_2CCMe_3) _4 (NITPh)] _n (BF_4) _n (NITPh=2-Phenyl-4, 4, 5, 5-tetramethyl-4, 5-dihydro-1H-imidazolyl-1-oxy-3-oxide)
- Chain and Discrete Dimer Complexes of Molybdenum(II) Trifluoroacetate Axially Coordinated by p-Quinones, [Mo_2(O_2CCF_3)_4(2,6-Me-BQ]_n(2,6-Me-BQ=2,6-dimethyl-p-benzoquinone)and [Mo_2(O_2CCF_3)_4(2,6-t-Bu-BQ)_2 (2,6-t-Bu-BQ=2,6-di-t-butyl-p-benzoquinone)
- Linear Chain Compounds of Molybdenum(II) Acetate Linked by Phyrazine, 4,4'-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane
- Structure and Magnetic Properties of a Nitroxide Diruthenium(II,III) Complex, [Ru_2(O_2CCMe_3)_4(tempo)_2] {Ru_2(O_2CCMe_3)_4(H_2O)_2](BF_4)_2(tempo=2,2,6,6,-Tetramethylpiperidine-1-oxyl)
- Structure and Properties of a Compound Formed by the Reaction of Molybdenum(II) Trifluoroacetate with 4,4'-Bipyridine
- A Novel Chain Compound Composed of Rhodium(II) Pivalate Dimer and 1,4-Benzoquinone
- "Miocene calcareous nannofossils of the Bihoku group in the Shobara area, Hiroshima prefecture, southwest Japan"
- Preparation, Characterization, and Electrochemical Properties of Tris(2,3,9,10,16,17,23,24-octabutoxyphthalocyaninato)diytterbium(III) and -didysprosium(III)
- Preparation of One Structural Isomer of Tetra-substituted Phthalocyanine, 1, 8, 15, 22-Tetra(3'-pentoxy)phthalocyanine, and a Crystal Structure of Its Nickel(II) Complex
- Preparation and Clinical Evaluation of Streptokinase Jelly for Intractable Decubitus and Skin Ulcer
- Roles of SiH_3 and SiH_2 Radicals in Particle Growth in rf Silane Plasmas
- Effects of Dilution Gases on Si Atoms and SiHx^^+ (X = 0-3) Ions in Electron Cyclotron Resonance SiH_4 Plasmas
- HI-Mediated Cyclization of o-Alkynylstyrenes
- Synthesis and Structure of a Germylene Bearing a 1, 8-Dimethoxyanthracene Ligand
- Synthesis of a New Tridentate Anthracene Ligand Bearing (i-Pr9_2P Group at 1,8-Positions: Facile Bond Switch on Tetracoordinate Boron Atom
- Structure of Intrinsic States of K^π=0^+ Bands in ^Ne : Study of Transient Character
- Histological distribution of FR-1, a cyclic RGDS-peptide, binding sites during early embryogenesis, and isolation and initial characterization of FR-1 receptor in the sand dollar embryo
- Synthesis of RGDFPASS-containing Cystine Peptides and Isolation of RGD-recognizing Receptor in Sand Dollar Embryo by the Peptide-Affinity Chromatography
- Structure and Activity of Fibronectin-related Peptides. The Role of Amino Acid Residues of Positions 5 and 6 in RGDSPASS-containing Cyclic Decapeptide(FR-1)
- The dansyl Group as a Molecular Probe for the Histochemical Localization of a Synthetic Fibronectin-related Peptide
- Design and Synthesis of Fibronectin-related Peptides. Ala-analogs of RGDSPASS Containing Cystine Peptide (FR-1)
- Design and Synthesis of Cyclic Fibronectin Related Peptides, RGDSPASS Containing Cystine Peptides
- A Chain Compound Built Up by Alternated Arrangement of Molybdenum(II) Trifluoroacetate Dimer and 9,10-Anthraquinone
- Reaction Matrix Theory for Cluster States in Light Nuclei. II : Clustering Dependence of the Effective Interaction
- Reaction Matrix Theory for Cluster States in Light Nuclei. I : Be^8
- Application of Variational Principle with Natural Boundary Condition to Scattering in Generator Coordinate Method
- Synthesis of Fibronectin Related Peptides : N^α-Methyl Amino Acid-containing Peptides
- Realistic Effective Interaction between Nucleons in Cluster State of Light Nuclei : Starting-Energy-Dependent Interaction and Its Application to Alpha-Cluster plus ^O-Core Model of ^Ne
- Roles of SiH3 and SiH2 Radicals in Particle Growth in rf Silane Plasmas
- The color isomerism of oxovanadium(IV) complexes with tetradentate schiff base.
- The nucleophilic substitution of dicarboxylic imides on the chelate ring of tris(3-bromo-2,4-pentanedionato)iron(III).
- A kinetic study of the reactions of several cobalt(III) complexes with ascorbic acid.
- The preparation and some properties of cobalt(II) Schiff base complexes and their molecular oxygen adducts.
- The preparation and some properties of 3-substituted 2,4-pentanedionato metal(II, III) complexes.
- Intra- and intermolecular electron-transfer reaction of viologen-linked copper(II) Schiff base complexes.
- Partial Oxidation of (Octakis(dodecyloxy)phthalocyaninato)zinc(II) with 2,3-Dichloro-5,6-dicyano-p-benzoquinone.
- Chemical Oxidation of Tetra-t-butylphthalocyanine and Its Complexes with Cobalt(II), Nickel(II), Copper(II), and Zinc(II).
- Preparation and Properties of Dimeric Dialkoxo-bridged Chromium(III) Complexes with 3-Bromo-2,4-pentanedione
- The reduction of cobalt(III) complexes by ascorbic acid. II. The kinetics and mechanisms of the reactions of diaqua and aquahydroxo macrocyclic N4 complexes.
- A kinetic study of the anation reactions of some cobalt(III) complexes containing macrocyclic quadridentate amine ligands.