The reaction of O(3P) atoms with indene and phenanthrene induced by the .GAMMA.-radiolysis of liquid carbon dioxide.
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概要
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The γ-radiolysis of liquid CO<SUB>2</SUB> with indene and phenanthrene gives the corresponding oxirane and carbonyl compounds, together with some products which are unexpected on the basis of the reaction of (<SUP>3</SUP>P) with aliphatic olefins: (i) the corresponding cyclic carbonate; (ii) 1<I>H</I>-2-benzopyran and a dimer for indene, and (iii) dibenz[<I>b</I>,<I>d</I>]oxepin and 2,2′-biphenyldicarbaldehyde for phenanthrene. The mechanisms of the formation of these products are discussed.
- 公益社団法人 日本化学会の論文
著者
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Takamuku Setsuo
The Institute Of Scientiffic And Industrial Research Osaka University
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SAKURAI Hiroshi
The Institute of Scientific and Industrial Research, Osaka University
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Hori Akira
The Institute of Scientific and Industrial Research, Osaka University
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Goto Seizi
The Institute of Scientific and Industrial Research, Osaka University
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