The reactions of several anilides with phosphoryl chloride.
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概要
- 論文の詳細を見る
Chloroacetanilide and <I>p</I>-methylchloroacetanilide reacted with phosphoryl chloride to give 2-chloromethyl-3-chloro-4-anilinoquinoline and 2-chloromethyl-3-chloro-4-(<I>p</I>-toluidino)-6-methylquinoline respectively. In the case of propionanilide, 2-ethyl-3-methyl-4-anilinoquinoline was obtained when the reaction was carried out at 20–30 °C. On the other hand, when the reaction temperature was raised to 80–100 °C, <I>N</I>-(1-chloro-1-propenyl)-<I>N</I>,<I>N</I>′-diphenylacetamidine was obtained.
- 公益社団法人 日本化学会の論文
著者
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FUKUDA Masahiro
The Institute of Scientific and Industrial Research, Osaka University
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SAKURAI Hiroshi
The Institute of Scientific and Industrial Research, Osaka University
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Okamoto Yoshiki
The Institute Of Scientific And Industrial Research Osaka University
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