Surface-active properties and their photochemical behaviors of (1-alkyl-4-pyridiniomethyl)phosphonates.
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概要
- 論文の詳細を見る
(1-Alkyl-4-pyridiniomethyl)phosphonates bearing long alkyl-chains of even carbon numbers of 8 to 18 were prepared. They exhibited the characteristics of surface-active agents. Upon irradiation in alkaline aqueous media, the phosphonates underwent the C–P bond cleavage to give 1-alkyl-4-methylpyridinium phosphates and as a result the surface tension of the solution also changed. The two-fold increases of the quantum yields of the C–P bond cleavage were found at their critical micelle concentrations.
- 公益社団法人 日本化学会の論文
著者
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Takamuku Setsuo
The Institute Of Scientiffic And Industrial Research Osaka University
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Okamoto Yoshiki
The Institute Of Scientific And Industrial Research Osaka University
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Hosoda Asao
The Institute of Scientific and Industrial Research, Osaka University
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