Photochemical hydroxymethylation of alicyclic and aliphatic alkenes induced by a EuIII/EuII photoredox system in methanol.
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概要
- 論文の詳細を見る
The photoirradiation of a methanol solution of EuCl<SUB>3</SUB> and alkenes such as cyclohexene, cyclooctene, cyclododecene, and tetramethylethylene afforded (hydroxymethyl) alkane. The dihydro dimer of alkene, hydrogen, and ethylene glycol are also formed. Reactions proceed via a radical mechanism induced by hydrogen atoms and hydroxymethyl radicals, which are produced by a photoredox reaction of Eu<SUP>III</SUP>/Eu<SUP>II</SUP> in methanol.
- 公益社団法人 日本化学会の論文
著者
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Ishida Akito
The Institute Of Scientiffic And Industrial Research Osaka University
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Takamuku Setsuo
The Institute Of Scientiffic And Industrial Research Osaka University
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Yamashita Shinya
The Institute of Scientific and Industrial Research, Osaka University
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Toki Susumu
The Institute of Scientific and Industrial Research, Osaka University
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