Photochemical reactions of aromatic compounds. XXIX. Photochemical and thermal cycloreversions of 1,2,2a,8b-tetrahydrocyclobuta[a]naphthalenes.
スポンサーリンク
概要
- 論文の詳細を見る
Photochemical and thermal cycloreversions of 1,2,2a,8b-tetrahydrocyclobuta[<I>a</I>]naphthalenes were investigated. The cycloreversion in the excited singlet state was completely stereospecific; a concerted mechanism was assigned. The benzophenone-sensitized and thermal decomposition gave a mixture of <I>cis</I>- and <I>trans</I>-olefins, but favored stereoretention. The mechanisms are discussed in terms of singlet and triplet 1,4-biradicals.
- 公益社団法人 日本化学会の論文
著者
-
SAKURAI Hiroshi
The Institute of Scientific and Industrial Research, Osaka University
-
Pac Chyongjin
The Institute of Scientific and Industrial Research, Osaka University
-
Mizuno Kazuhiko
The Institute of Scientific and Industrial Research, Osaka University
関連論文
- Synthesis of 1-Dialkylaminoalkylidenediphosphonic Acids and Their Properties for Complex Formation
- Synthesis of Dialkylaminomethylenediphosphonic Acids
- The reactions of several anilides with phosphoryl chloride.
- A Novel Preparation of Enamine Phosphonates from Ketene O,N-, S,N- and N,N-Acetals with Diethyl Phosphite
- Reactions of aromatic radical anions with benzhydryl chloride studied by pulse radiolysis.
- The Photolysis of 1,3-Cyclootadiene Vapor. Vibrationally Excited Molecules Produced by the Photoelimination of Ethylene
- Pyrolysis of Tris (2,3-dibromopropyl) Phosphate and Its Related Compounds
- The Pyrolysis of Hexyl Phosphates and Their Salts
- Photochemical Studies of the Esters of Aroylphosphonic Acids
- Pyrolysis of Dialkyl 2-Acyloxyalkylphosphonates
- The Structure and Reactivity of Organic Ions in Gas-phase Radiolysis. VIII. The C7H7+ Ion from Toluene and Ethylbenzene
- Photochemical reactions of aromatic compounds. XXXIII. Photoreactions of 1-cyanonaphthalene with indene in various solvents.
- Photochemical Reactions of Aromatic Compounds. XVII. The Photocyclization of N-(o-Chlorobenzyl)aniline
- Photochemical reactions of aromatic compounds. XXIX. Photochemical and thermal cycloreversions of 1,2,2a,8b-tetrahydrocyclobuta[a]naphthalenes.
- Photochemical reactions of aromatic compounds. XXXVI. The photoreactions of anthracene with some selected tertiary aromatic amines in polar media.
- Photochemical reactions of aromatic compunds. XXXI. Exciplex quenching by pyridine, methylated pyridines, and methylated imidazoles and termolecular interaction in the excited singlet state.
- Formation of Phosphate Derivatives by the Reaction of Propyl and Allyl Halides with Phosphorus Trichloride and Oxygen
- The reaction of O(3P) atoms with indene and phenanthrene induced by the .GAMMA.-radiolysis of liquid carbon dioxide.
- Selenium Catalyzed Synthesis of of Carbonates. The Reaction of Alkoxide with Carbon Monoxide and Oxygen in the Presence of Selenium