Studies on diazo type process. VI. Physico-chemical studies on 1-(p-dimethylaminophenylazo)-2-naphthol-3,6-disulfonic acid in aqueous solutions.
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概要
- 論文の詳細を見る
1-(<I>p</I>-Dimethylaminophenylazo)-2-naphthol-3,6-disulfonic acid is formed in many important commercial "dry process" diazo-printing. Some physico-chemical properties of this dye in solutions have been investigated. Its absorption spectra in various solvents and in water at various acidities have been discussed on the basis of azoquinone hydrazone tautomeric and acid-base equilibria respectively. The dissociation constants of the acid-base equilibria in the pH range of 1–14 in aqueous solutions have been determined at 25 °C and 1.0 M ionic strength. Conductivities of aqueous solutions at various concentrations and temperatures have been interpreted on the basis of the colloidal nature of the dye. The polarograms of the compound have been drawn at various pH's and discussed. Polarographic method indicates complex formation between Zn(II) salt and the dye in the mole ratio of 1:2.
- 公益社団法人 日本化学会の論文
著者
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Suzuki Shin
Department Of Cardiology Nagasaki Citizens Hospital
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Harada Kieko
Department of Materials Technology, Faculty of Engineering, Chiba Univercity, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
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Das Rebati
Department of Synthetic Chemistry, Faculty of Engineering, Chiba University
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Suzuki Shin
Department of Image Science and Engineering, Faculty of Engineering, Chiba University
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Harada Kieko
Department of Image Science and Engineering, Faculty of Engineering, Chiba University
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Harada Kieko
Department of Computer Science, Kitami Institute of Technology
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Das Rebati
Department of Image Science and Engineering, Faculty of Engineering, Chiba University
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