Synthesis and characterization of (salicylideneaminoalkyl)phosphonatocopper(II) and [(N-salicylideneglycylamino)alkyl]phosphonatocopper(II).
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概要
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The titled compounds have been synthesized by a template reaction of aminoalkylphosphonic acids or glycylaminoalkylphosphonic acids and salicylaldehyde with copper(II) ion. The square-planar structures have been proposed by analogy with corresponding structures of <I>N</I>-salicyclideneglycine or <I>N</I>-salicylideneglycylglycine chelates. The deprotonated peptide nitrogen coordination was confirmed by IR-spectra for the phosphonopeptides chelates.
- 公益社団法人 日本化学会の論文
著者
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Murase Ichiro
Laboratory of Chemistry, College of General Education, Kyushu University
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Martell Arthur
Department of Chemistry, Texas A & M University
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- The crystal structures of a dicopper(II) complex containing two N4-macrocyclic rings connected with an ethylene chain.
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