A proton conductive coordination polymer. I. [N,N'-bis(2-hydroxyethyl)-dithiooxamido]copper(II).
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概要
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In a family of <I>catena</I>-μ-<I>N</I>,<I>N</I>′-disubstituted dithiooxamidocopper(II) complexes which have been assumed as two-dimensional coordination polymers, one complex with HOC<SUB>2</SUB>H<SUB>4</SUB>- substituents is an electronic conductor as well as others, and also a protonic conductor uniquely. The latter property was proved both by spectroscopic detection of the hydrogen molecules evolved from d.c. electrolysis of pressed pellets of the powder specimen and by observation of the anomalous increase (three orders of magnitude) of the electric conductivity as an effect of 10<SUP>3</SUP> Pa of H<SUB>2</SUB>O or D<SUB>2</SUB>O vapor on the dehydrated specimen in an evacuated conductivity cell. A novel conduction mechanism was suggested for such a solid system with both conjugated double bonds and extended hydrogen bonds.
- 公益社団法人 日本化学会の論文
著者
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Yamashita Kenichi
Department Of Applied Chemistry School Of Engineering Kyushu University
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Kanda Seiichi
Department of Applied Chemistry, Faculty of Engineering, Tokushima University
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Ohkawa Kuwako
Department of Applied Chemistry, Faculty of Engineering, Tokushima University
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Kanda Seiichi
Department of Applied Chemistry, Faculty of Engineering, The University of Tokushima
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Ohkawa Kuwako
Department of Applied Chemistry, Faculty of Engineering, The University of Tokushima
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