Studies on Riboflavin Tetranicotinate:I. Its Synthesis and Physicochemical Properties
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概要
- 論文の詳細を見る
Riboflavin 2′, 3′, 4′, 5′-tetranicotinate (m. p. 147-150°) was synthesized by direct acylation of riboflavin with nicotinyl chloride and its chemical and physical properties were reported. Molar extinction coefficients of its benzene solution at 344, 445 and 471mμ were determined to be 8.5×103, 12.5×103 and 9.7×103 cm-1M-1, respectively. Emission maximum of the solution, when excited at 360mμ, was found at 524mμ. This compound was found to be soluble in various organic solvents, such as benzene, chloroform, alcohols, ketones, esters including triglycerides, dioxane and so on. However, its solubility in water (at neutral pH) was somewhat less than that of riboflavin. It showed considerable resistance to photo-decomposition at neutral pH, as compared with free riboflavin.
- 日本ビタミン学会の論文
著者
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八木 国夫
Institute of Biochemistry, Faculty of Medicine, University of Nagoya
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小滝 祥
Institute of Biochemistry, University of Nagoya
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小滝 祥
Institute of Biochemistry, Faculty of Medicine, University of Nagoya
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