酢酸水銀付加法による飽和, 不飽和アルコールの分離 : 高級アルコールに関する研究 (第3報)

概要

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The authors could confirm the separation of unsaturated alcohols from saturated alcohols on thinlayer chromatography (TLC) by making adduct with mercuric acetate.<BR>Experiments were carried out with three groups of samples, mercuric acetate-adducted oleylal cohol and stearylalcohol, the adducted oleyl acetate and stearyl acetate, and the adducted sperm whale alcohols, by using Silica gel G as the adsorbent, and bezene, toluene, xylene and other solvents as the developing agents.<BR>Benzene, toluene and xylene were better developers than other solvents tested.<BR>Acetylated alcohols gave better separation of saturated and unsaturated alcohols than that of untreated ones.<BR>Silica gel G was found as suitable adsorbent for the purpose.
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