電気化学的手法によるポリピロールの形態制御

概要

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By controlling electrochemical polymerization conditions conductive polymers have been fabricated not on the electrode but on the bottom of the electrochemical cell or in the electrolyte with needle-plane electrode structure. Poly(pyrrole), PPy with a fractal form has been successfully prepared by an electrochemical polymerization technique. The growth form of conductive polymer has been investigated as the effect of the composition of the electrolyte, that is, the kind of solvent, the kind of supporting electrolyte, and the monomer, and the difference in the concentrations, especially the effect of basic properties of the solvent such as the polarity (relative polarity measure), basicity (nucleophilic nature), that is, donor number, in addition, viscosity, relative permittivity, etc.
社団法人電気学会の論文