A1 超音波反応場を利用したリチウムイオン電池用鉄系正極材料の設計

概要

論文の詳細を見る
The Olivine-type LiFePO_4 was prepared by sonochemical method starting from LiOH・H_2O, (NH_4)_2HPO_4 and FeSO_4・7H_2O. Ultrasonic irradiation upon the solution of raw materials was able to synthesize fine particles of LiFePO_4 and prohibit the conversion of Fe^<2+> to Fe^<3+> in the solution without using a reducing agent. The prepared LiFePO_4 was characterized by XRD and SEM. The shape of the sample was a globular structure and the particle size of that was homogeneous and under sub-micron. The temperature of the solution is an important factor to synthesis LiFePO_4 by the sonochemical reaction. Discharge behavior of LiFePO_4 synthesized sonochemical reaction at 60℃ of the solution temperature exhibited 113mAhg^<-1> in the range of 4.0-3.0V vs. Li/Li^+ at a current rate of 0.2C. The ultrasonic effects on the precipitation of the LiFePO_4 precursor in the solution are very complicated, but one of them may helps nucleation of the LiFePO_4 precursor as a consequence of the collision among solute raw materials.
日本ソノケミストリー学会の論文
2007-12-06