Components of the carrier solvents and separation performance in the tube radial distribution chromatography using a fused-silica capillary tube
スポンサーリンク
概要
- 論文の詳細を見る
A novel capillary chromatography system has been developed using an open capillary tube and a water-hydrophilic-hydrophobic organic solvent mixture carrier solution; the system is called tube radial distribution chromatography. In this study, we prepared various types of the carrier solution of the water-ethyl acetate (hydrophobic organic solvent) mixture including dioxane, 1-propanol, ethanol, acetonitrile, or methanol as a hydrophilic organic solvent, and examined their separation performance in the system using a fused-silica capillary tube. A mixture analyte of 1-naphthol and 2,6-naphthalenedisulfonic acid was adopted as a model and injected into the fused-silica capillary tube in the system. The analytes were well separated with the water-1-propanol-ethyl acetate mixture (volume ratio 2:3:6), the water-ethanol-ethyl acetate mixture (2:2:6), and the water-acetonitrile-ethyl acetate mixture (3:8:4) carrier solutions. 1-Naphthol was first eluted from the capillary tube, followed by 2,6-naphthalenedisulfonic acid. However, the analytes were not separated with the water-dioxane-ethyl acetate mixture (4:11:11) or the water-methanol-ethyl acetate mixture (2:2:9). The data obtained here indicated an extension in preparation of the carrier solution by using several hydrophilic organic solvents and provided insight regarding carrier solvent behavior based on the tube radial distribution in the system.
著者
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Hashimoto Masahiko
Department of Chemical Engineering and Materials Science, Faculty of Science and Engineering, Doshis
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Tsukagoshi Kazuhiko
Department Of Chemical Engineering And Materials Science Faculty Of Engineering Doshisha University
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Tsukagoshi Kazuhiko
Department Of Chemical Engineering And Materials Science Faculty Of Science And Engineering Doshisha
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Tsukagoshi K
Doshisha Univ. Kyoto Jpn
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Tsukagoshi Kazuhiko
Dep. Of Chemical Engineering And Materials Sci. Fac. Of Engineering Doshisha Univ. Kyotanabe Kyoto 6
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Tsukagoshi K
Doshisha Univ. Kyotanabe
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塚越 一彦
Department Of Chemical Engineering And Materials Science Faculty Of Engineering Doshisha University
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Hashimoto M
Department Of Polymer Science And Engineering Faculty Of Textile Science Kyoto Institute Of Technolo
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Tsukagoshi Kazuhiko
Department Of Chemical Engineering And Materials Science Faculty Of Science And Engineering Doshisha
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Jinno Naoya
Department Of Chemical Engineering And Materials Science Faculty Of Science And Engineering Doshisha
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Hayashi Yoichiro
Department Of Chemical Engineering And Materials Science Faculty Of Science And Engineering Doshisha
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Hashimoto Masahiko
Department Of Chemical Engineering And Materials Science Faculty Of Science And Engineering Doshisha
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Tsukagoshi Kazuhiko
Doshisha Univ. Kyoto Jpn
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Tsukagoshi Kazuhiko
Department Of Chemical Engineering And Materials Science Doshisha University
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Hashimoto Masahiko
Department Of Chemical Engineering And Materials Science Doshisha University
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