411 CFRPの高分子マトリクスにおける硬化収縮の定量的評価(高分子/高分子基複合材料)

概要

論文の詳細を見る
Applying CFRP to precision machinery components and aerospace materials, CFRPs long-time dimensional accuracy must be secured. Matter for consideration about the dimensional accuracy, moisture absorption, chemical shrinkage, and visco-elastic deformation such as creep are presumable to be the leading factor for the deformation. These deformations are very small, so we need to evaluate quantitative analysis with these factors individually. In this study, we deal with the chemical shrinkage. First, we conducted dynamic DSC measurement to determine the total heat of reaction. Heat of reaction during the cure was measured by isothermal DSC measurement and was quoted to define the extent of cure. A Kinetic model, the Arrhenius model was applied to predict the extent of cure. Our aim is to evaluate the dimensional change concurrent with the cure of epoxy by using laser confocal displacement meter.
2006-11-25