Hexyl 2-Formyl-3-hydroxybenzoate, a Fungitoxic Cuticular Constituent of the Bulb Mite Rhizoglyphus robini(Organic Chemistry)

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概要

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• The cuticular constituent of the bulb mite Rhizoglyphm robini is revealed to be hexyl 2-formyl-3-hydroxybenzoate (1) [hexyl rhizoglyphinate as the trivial name]. Structural proof of this novel ester relied on MS, GC-FTIR and NMR spectral data. The total synthesis of compound 1 was achieved in two steps, first by formylating methyl 3-hydroxybenzoate with hexamethylenetetramine in 75% polyphosphoric acid to give methyl 2-formyl-3-hydroxybenzoate, and then by a TsOH-catalyzed transesterification of the product with hexanol in benzene. Much higher antifungal activity than that of citral is demonstrated for compound 1. although its activity is lower than that of acaridials.

• 社団法人日本農芸化学会の論文
• 1990-10-23

著者

• Leal W

  Institute Of Applied Biochemistry University Of Tsukuba:(present Office)national Institute Of Sericu

• Leal Walter

  National Institute Of Sericultural And Entomological Science

• Leal Walter

  Institute Of Applied Biochemistry University Of Tsukuba:(present Office)national Institute Of Sericu

• KUWAHARA Yasumasa

  Institute of Agriculture and Forestry, University of Tsukuba

• SUZUKI Takahisa

  Institute of Applied Biochemistry, University of Tsukuba

• Kuwahara Yasumasa

  Laboratory Of Chemical Ecology Graduate School Of Agriculture Kyoto University

• Leal W

  Univ. California Davis Ca Usa

• Sakata T

  Pesticide Research Institute Faculty Of Agriculture Kyoto University

• Suzuki Takahisa

  Institute Of Applied Bichemistry University Of Tsukuba

• Kuwahara Yasumasa

  Institute Of Agriculture And Forestry University Of Tsukuba

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