Acid-Induced Rearrangement of Triterpenoid Hydrocarbons Belonging to the Hopane and Migrated Hopane Series(Organic,Chemical)
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概要
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The acid-catalyzed rearrangement of triterpenoid monoenes belonging to the hopane and migrated hopane series with sulfuric acid and boron trifluoride etherate was investigated. By selecting the reaction conditions, a variety of the monoenes of these series, including three new compounds, 9βH-fern-7-ene (3c), 8βH-fern-9(11)-ene(4b), and adian-5(10)-ene(5b), were obtained. For comparison, oleanenes and migrated oleanenes were also subjected to the same reaction.
- 公益社団法人日本薬学会の論文
- 1987-07-25
著者
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上田 博之
昭和薬大
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上田 博之
Showa College of Pharmaceutical Sciences
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荒井 洋子
Showa College of Pharmaceutical Sciences
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塩島 憲司
Showa College of Pharmaceutical Sciences
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上田 博之
Showa Coll. Pharmaceutical Sci. Tokyo Jpn
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