合成イモゴライトの触媒性質の検討

概要

論文の詳細を見る
Imogolite is tubular clay mineral with typical chemical composition of (OH)_3Al_2O_3SiOH. Catalytic property of the synthetic imogolite was examined by the isomerization reaction of α-pinene and the oxidation reaction of cyclohexene using hydroperoxide. The acid property of imogolite was not detected by the isomerization reaction of α-pinene. Results of oxidation reaction of cyclohexene indicated that imogolite has the potential of concentration and plays as a field of reaction to increase collision frequency of reactants. Epoxidation of cyclohexene was observed by reaction using imogolite and acetonitrile as solvent.
日本粘土学会の論文
2006-05-29