Polarographic and emf Studies of the Reaction between Ethyl Xanthate and Cadmium (II) ion

スポンサーリンク

概要

• 論文の詳細を見る

• The reduction of cadmium (II) ion in the presence of excess of potassium ethyl xanthate was studied on the dropping mercury electrode, and emf measurements were carried out by using cadmium amalgam electrode. The d. c. polarogram gave a well-defined wave which corresponded to the one of reduction of cadmium (II) ion to cadmium amalgam. By employing polarographic method, the composition of a complex between ethyl xanthate and cadmium (II) ions was found to be Cd (EX)_4^<2-> (β_4=4×10^<11>). From emf measurements, nearly the same results were obtained without any assumption, and the absence of Cd (EX)_3^- was suggested.

• 東北大学の論文

著者

• Nanjo Michio

  The Research Institute Of Mineral Dressing And Metallurgy

• YAMASAKI Taro

  The Research Institute of Mineral Dressing and Metallurgy

• Yamasaki Taro

  The Research Institute Mineral Dressing And Metallurgy

関連論文

• Heterocyclic Compounds Containing Phosphorus. II : On the Formation and Cleavage of Cyclic Thiophosphates
• Polarographic and emf Studies of the Reaction between Ethyl Xanthate and Cadmium (II) ion
• Heterocyclic Compounds Containing Phosphorus. I : On the Syntheses of Five Membered Monothio Phosphates
• On the Preparation and the Properties of Alkyl Phosphorothionates (RO)_2P (S) H
• Studies of Xanthate Complexes by Solubility Method

スポンサーリンク