Heterocyclic Compounds Containing Phosphorus. II : On the Formation and Cleavage of Cyclic Thiophosphates

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概要

• 論文の詳細を見る

• Ethane-1, 2-bis-(dichlorothiophosphate) was prepared by the action of phosphorus sulfochloride on sodium ethylene diglycoholate. Cyclic chlorothiophosphates reported in previous manuscribt were synthesised by the reaction between phosphorus sulfochloride and sodium monoglycoholates derived from the corresponding glycohols. Attempts to lead the chlorothiophosphates to tertiary thiophosphates with sodium ethoxide resulted in failure because of the formation of ring cleavaged products. The products may have a structure of OH-CH_2-CH__-__R-OP(S)(OR)_2 or OH-CH__-__R-CH_2-OP(S)(OR)_2, where R represents alkyl radical and R do alkyl or hydrogen. The rates of esterification showed that the products had the structure of the latter except where R was hydrogen.

• 東北大学の論文

著者

• Sato Toshiro

  The Research Institute Of Mineral Dressing And Metallurgy

• YAMASAKI Taro

  The Research Institute of Mineral Dressing and Metallurgy

• Yamasaki Taro

  The Research Institute Mineral Dressing And Metallurgy

関連論文

• Heterocyclic Compounds Containing Phosphorus. II : On the Formation and Cleavage of Cyclic Thiophosphates
• Polarographic and emf Studies of the Reaction between Ethyl Xanthate and Cadmium (II) ion
• Heterocyclic Compounds Containing Phosphorus. I : On the Syntheses of Five Membered Monothio Phosphates
• On the Preparation and the Properties of Alkyl Phosphorothionates (RO)_2P (S) H
• Studies of Xanthate Complexes by Solubility Method

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