Enhanced Infrared Intensity of Benzene-Iodine Complex
スポンサーリンク
概要
- 論文の詳細を見る
It is shown that an enhancement of infrared absorption bands observed in the molecular complex is due to change in vertical ionization energy of electron donor in the course of molecular vibrations. An enhanced infrared absorption intensity of 992 cm^<-1> of benzene in benzene-iodine complex is calculated by a semi-empirical molecular orbital theory and the charge transfer theory of Mulliken, and also using the dipole moment value of benzene-iodine complex measured by Fairbrother. The calculated intensity value agrees well with the experimental value by Ferguson and Matsen.
- 東北大学の論文
著者
-
Watari Fumio
The Chemical Research Institute Of Non-aqueous Solutions
-
KINUMAKI Susumu
The Chemical Research Institute of Non-Aqueous Solutions
関連論文
- Infrared Absorption Spectra of Molecular Complexes of Pyridine. Part V : Molecular Complexes with Cu-, Co-, Ni- and Mn-Dihalides
- Infrared Absorption Spectra of Molecular Complexes of Pyridine. Part IV : Molecular Complexes with Zn-, Cd-, and Hg-Halides
- Infrared Absorption Spectra of Molecular Complex of Pyridine. Part II : Molecular Complexes with Some Group V Halides
- Infrared Absorption Spectra of Molecular Complexes of Pyridine. Part III : Molecular Complexes with Iodine and Iodine Halides
- Enhanced Infrared Intensity of Benzene-Iodine Complex
- Infrared Intensities of Nitrous Oxide
- Infrared Spectra of Some Troponoid and Aromatic Compounds adsorbed on Column Chromatogram
- On the Diffusion of Silver into Glass
- Infrared Spectra of Troponoid Compounds. I : Tropone and Tropolone
- Raman Spectra of Liquid Ammonia Solutions. II : Liquid NH_3-CCl_4 System
- Raman Spectra of Liquid Ammonia Solutions. I : Raman Spectrum of Liquid Ammonia and Its Force Constants
- Raman Spectra of Liquid Ammonia Solutions. III : Liquid NH_3-CH_3OH and Liquid NH_3-C_2H_5OH Systems