Observation and Analysis of the Δv=5 Stretch Overtone Band Transition of ^<15>NH_3
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概要
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The absorption spectra of the Δv=5 stretch overtone band transition of ^<15>NH_3 in the visible region (648 nm band) are observed by the photoacoustic method for the first time. The resolution is 0.01 cm^<-1>. The observed Stark spectra at electric field high enough to resolve M components are helpfully employed in assignment of the rotation and inversion transitions. The vibrational level structure is well explained in terms of the local mode theory. The rotational constants and isotope shift are obtained.
- 社団法人応用物理学会の論文
- 1991-11-15
著者
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MORIWAKI Yoshiki
Department of Physics, Faculty of Science, The University of Tokyo
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Nakagawa Ken'ichi
Department Of Physics Faculty Of Science The University Of Tokyo:(present Address)graduate School At
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Shimizu Tadao
Department Of Electronics And Computer Science Science University Of Tokyo In Yamaguchi
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Moriwaki Y
Inst. Molecular Sci. Okazaki Jpn
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Moriwaki Yoshiki
Department Of Molecular Structure Institute For Molecular Science
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