COPRECIPITATION BEHAVIOR OF AMINO ACIDS WITH Zn-Al LAYERED DOUBLE HYDROXIDE PRECIPITATES
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概要
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The coprecipitation of various amino acids (phenylalanine: Phe, alanine: Ala, leucine: Leu, tryptophan: Trp, histidine: His and aspartic acid: Asp) into the Zn-Al layered double hydroxide (LDH) was quantitatively investigated at 40℃. When Phe was used as a guest amino acid, the coprecipitation was influenced by the solution pH, Zn/Al/Phe molar ratio and kind of coexisting inorganic ion. The optimum conditions were reaction time: 1 h, pH range: 7-9 and Zn/Al/Phe molar ratio: 2-4/0.5-1/1, in which Phe was thought to be intercalated into the Zn-Al LDH precipitates as zwitterion. In the (Cl, Phe)/Zn-Al LDH and Phe/Zn-Al LDH precipitates, the basal spacing of (003) was observed at 7.8Å (using chloride reagent) and 18.8Å (using nitrate reagent), respectively. It suggests that the intercalated Phe was oriented horizontally or vertically for the Zn-Al LDH basal layer, in which the arrangement was dependent on the charge density of coexisting inorganic ions. In the case of various other amino acids, the coprecipitation greatly influenced by the kind of side-chain of the amino acids. The amino acids having hydrophobic side-chain (Leu and Trp) were preferentially intercalated into the LDH interlayer as zwitterion. Moreover, in the deintercalation experiments of Phe from the Phe/Zn-Al LDH precipitate, Phe was easily deintercalated by the ion exchange with CO_3^<2-> ion.
- 日本粘土学会の論文
著者
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Takahashi Satoshi
Department Of Urology Sapporo Medical University School Of Medicine
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AISAWA SUMIO
Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate Uni
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NARITA EIICHI
Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate Uni
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Aisawa Sumio
Department Of Frontier Materials And Function Engineering Graduate School Of Engineering Iwate Unive
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Narita E
Department Of Frontier Materials And Function Engineering Graduate School Of Engineering Iwate Unive
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Narita Eiichi
Department Of Applied Chemistry And Molecular Science Faculty Of Engineering Iwate University
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UMETSU Yoshio
Department of Chemical Engineering, Iwate University
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OGASAWARA WATARU
Department of Chemical Engineering, Faculty of Engineering, Iwate University
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Takahashi Satoshi
Department Of Hematology The Institute Of Medical Science The University Of Tokyo
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Takahashi S
秋田県農林水産技術センター総合食品研究所
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Sasaki A
Facuty Of Engineering Shizuoka Univeisty
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Umetsu Y
Department Of Chemical Engineering Iwate University
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Umetsu Yoshio
Department Of Applied Chemistry And Molecular Science Faculty Of Engineering Iwate University
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Sasaki A
Department Of Frontier Materials And Function Engineering Graduate School Of Engineering Iwate Unive
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Ogasawara Wataru
Department Of Applied Chemistry And Molecular Science Faculty Of Engineering Iwate University
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Ogasawara Wataru
Department Of Chemical Engineering Faculty Of Engineering Iwate University
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Takahashi Satoshi
Departmanets Of Immunology Graduate School Of Medical And Dental Sciences Niigata University
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