INTERCALATION OF POLYHYDRIC ALCOHOLS INTO Mg-Al LAYERED DOUBLE HYDROXIDE BY CALCINATION-REHYDRATION REACTION
スポンサーリンク
概要
- 論文の詳細を見る
Layered double hydroxide (LDH) has an anion exchange property, and the intercalation of various organic molecules into LDH has been investigated in recent years. We have reported the intercalation of non-ionized guests such as pentose, hexose and cyclodextrin, into Mg-Al LDH by the calcination-rehydration reaction. In this paper, the intercalation behavior of non-ionized guests, various straight chain polyhydric alcohols (carbon number 3-5), into Mg-Al LDH by the same reaction has been examined. According to the XRD patterns and FT-IR spectra, the solid product was found to contain polyhydric alcohol and to show the restorable LDH structures. The amount of polyhydric alcohols intercalated was as follows: glycerin (C3)<erythritol (C4)<ribitol (C5)<arabitol (C5)<xylitol (C5) and greatly influenced by the conformation of C5 polyhydric alcohol isomers. It was confirmed that these polyhydric alcohols were intercalated into the LDH interlayer space by the formation of hydrogen bond between hydroxyl groups of guest polyhydric alcohols and the host LDH basal layer.
- 日本粘土学会の論文
著者
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HIRAHARA Hidetoshi
Department of Applied Chemistry, Faculty of Engineering, Iwate University
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Takahashi Satoshi
Department Of Urology Sapporo Medical University School Of Medicine
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AISAWA SUMIO
Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate Uni
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NARITA EIICHI
Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate Uni
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Aisawa Sumio
Department Of Frontier Materials And Function Engineering Graduate School Of Engineering Iwate Unive
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Narita E
Department Of Frontier Materials And Function Engineering Graduate School Of Engineering Iwate Unive
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Narita Eiichi
Department Of Applied Chemistry And Molecular Science Faculty Of Engineering Iwate University
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AKIYAMA TAKUMI
Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate Uni
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Hirahara Hidetoshi
Department Of Frontier Materials And Function Engineering Graduate School Of Engineering Iwate Unive
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Takahashi Satoshi
Department Of Hematology The Institute Of Medical Science The University Of Tokyo
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Takahashi S
秋田県農林水産技術センター総合食品研究所
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Sasaki A
Facuty Of Engineering Shizuoka Univeisty
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Akiyama Takumi
Department Of Frontier Materials And Function Engineering Graduate School Of Engineering Iwate Unive
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Sasaki A
Department Of Frontier Materials And Function Engineering Graduate School Of Engineering Iwate Unive
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Takahashi Satoshi
Departmanets Of Immunology Graduate School Of Medical And Dental Sciences Niigata University
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