Diterpenoids. XLIV. A-Ring Bromination of Abietane Skeleton and the Synthesis of Teideadiol
スポンサーリンク
概要
- 論文の詳細を見る
Direct introduction of bromine into the A-ring of the phenacylidene derivatives of l-abietic acid (1) was developed and it was applied to the conversion of 1 into teideadiol (2), a naturally occurring diterpene with a hydroxy group on the A-ring of its abietane skeleton.
- 公益社団法人日本薬学会の論文
- 1976-07-25
著者
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大澤 富彦
Rikagaku Kenkyusho (The Institute of Physical and Chemical Research)
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水野 博光
Rikagaku Kenkyusho (The Institute of Physical and Chemical Research)
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田原 昭
Rikagaku Kenkyusho (the Institute Of Physical Chemical Research)
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水野 博光
Rikagaku Kenkyusho (the Institute Of Physical And Chemical Research):(present Address)nichiban Co. L
関連論文
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- カイコへのアビエチン酸誘導体の経口投与による3眠蚕の出現
- Diterpenoids. XXXV. A-Ring Substitution of Hydrofluorene Compound derived from l-Abietic Acid
- Diterpenoids. XXXIV. Stereochemistry on the Rearranged Compound (Benzilic Acid Rearrangement) of Methyl 6,7-Dioxo-5α, 10α-podocarpa-8,11,13-trien-15-oate
- 23 Abietic Acidより2,3の天然物の合成研究
- 7 ベンゾニリデン型ジテルペンの転位反応
- ジテルペノイドの研究(第23報)ヒドロフルオレン誘導体の構造と甘味との関係および新甘味物質の改良合成法
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- Stereochemistry on the Rearranged Compound (Benzilic Acid Rearrangement) of Methyl 6,7-Dioxo-5α, 10α-podocarpa-8,11,13-trien-15-oate
- 39 松脂よりHydrofluorene誘導体の合成と立体構造 : 甘味性物質について
- Diterpenoids. XVI. Reduction of 6β-Hydroxy-enantio-podocarpa-8,11,13-trien-16-oic Acid Derivative
- Synthesis of 6β Hydroxy-tetrahydro-and-hexahydroenantio-deoxypodocarpic Acid
- 12 A環置換天然ジテルペノイドの合成
- Diterpenoids. XLV. Ozonolysis of Phenolic Dehydroabietic Acid Derivatives
- Diterpenoids. XLIV. A-Ring Bromination of Abietane Skeleton and the Synthesis of Teideadiol
- Diterpenoids. XLI. Rearrangement of Deisopropyl Phenacylidene Type Diterpene by Means of Aluminum Chloride
- Diterpenoids. XXXVII. Rearrangement of Methyl 13-Isopropyl-7-oxo-podocarpa-5,8,11,13-tetraen-15-oate by Means of Aluminum Chloride
- Diterpenoids. XXXI. Reaction of Methyl Dehydroabietate Derivatives with Aluminum Chloride under Effect of Electron-withdrawing Group. Synthesis of Methyl Deisopropyldehydroabietate Series
- Diterpenoids. XXX. Reaction of Methyl Dehydroabietate Derivatives with Aluminum Chloride under Effect of Electron-donating Group
- Diterpenoids. XXIX. Nitration of Methyl Dehydroabietate Derivatives
- Diterpenoids. XXVIII. Nitration of Methyl 7-Oxo-dehydroabietate Derivatives
- Novel Nitration Reaction of Methyl 7-Oxodehydroabietate
- 39 Diterpeneに於ける骨格の変換
- Diterpenoids. XLVI. Syntheses of Taxodione, Royleanone and Their Analogues
- 31 l-Abietic Acidよりd-Kaurene,d-Phyllocladene,l-Hibaeneの合成 : 13位Isopropyl基の変換
- Diterpenoids. XXXVI. Synthesis of d-Kaurene and d-Phyllocladene from l-Abietic Acid
- Transformation of l-Abietic Acid to Benzohydroazulene Derivative
- Diterpenoids. XXVII. Synthesis of 11-Methoxy-diterpenoids. (2). Synthesis of 11-Methoxy-dehydroabietic Acid Derivatives
- Diterpenoids. XXVI. Synthesis of 11-Methoxy-diterpenoids. (1). Synthesis of Antipodal 11-Methoxy-deoxypodocarpic Acid Derivatives
- Diterpenoides. XXI. Hydration of Stereoisomers of Dimethyl 1,2,3,4,5,10,11,14-Octahydro-4β, 10α-dimethyl-fluorene-4α, 6-dicarboxylate
- Diterpenoids. XX. Nitration of Dimethyl 1,2,3,10-Tetrahydro-4β, 10α-dimethyl-4H-fluorene-4α, 6-dicarboxylate and Its Hydrogenated Stereoisomers
- Diterpenoids. XVII. Epimerization at Lactonization of 6β-Hydroxy-enantio-podocarpan (and 8-monoen-) 16-oic Acid (cis-and trans-B/C-ring Juncture) Syntheses of the Corresponding 6α-Hydroxy Series
- Lactonization of 6β-Hydroxy-tetrahydro-and-hexahydro-enantio-deoxypodocarpic Acid. Synthesis of 6α-Hydroxy-tetrahydro-and-hexahydro-enantio-deoxypodocarpic Acid