Fluorinative Beckmann Frangmentation : Fluorinative α-Cleavage of Cyclic ketoximes by Diethylaminosulfur Trifluoride
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概要
- 論文の詳細を見る
Diethylaminosulfur trifluoride reacted with cyclic ketoximes bearing substituent(s) that can stabilize a carbocation to cause fluorinative fragmentation, affording fluorinated carbonitrile. Ketoximes lacking such substituents afforded complex mixtures. However, the intorduction of a sulfur functionality , which can stabilize a carbocatin and can be easily removed from teh reaction products, into the ketoxime was effective for producing the fluorinative fragmentation.
- 公益社団法人日本薬学会の論文
- 2000-02-01
著者
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MOMOSE TAKEFUMI
Faculty of Pharmaceutical Sciences, Kinki University
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Kirihara Masayuki
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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Kirihara Masayuki
Department Of Materials Science Shizuoka Institute Of Science And Technology
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Okumura M
Dep. Of Pharmacy Univ. Of Miyazaki Hospital
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OKUMURA Maiko
Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University
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NIIMI Kanako
Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University
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Niimi Kanako
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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Momose T
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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Momose Takefumi
Faculty Of Pharmaceutical Sciences Kinki University
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奥村 正文
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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