Oxidation of Indoles with Oxodiperoxomolybdenum (VI), MoO_5・HMPA. Preparation of 2-Hydroxyindoxyl and Isatogen Derivatives
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概要
- 論文の詳細を見る
Oxidation of 1-acetylindoles 1 with (hexamethylphosphoramide) oxodiperoxomolybdenum (VI), MoO_5・HMPA, in dry methylene chloride gave 1-acetyl-2-hydroxyindoxyls 4. 2-Phenylindole (8) was similarly treated with MoO_5・HMPA to give a dimeric product 11,while oxidation of 8 with three mol eq of MoO_5・HMPA gave 2-phenylisatogen (12). The oxidation of other indoles, 14,19,21,and 22,with MoO_5・HMPA in methylene chloride is also described. A possible mechanism for these oxidations is presented.
- 公益社団法人日本薬学会の論文
- 1985-05-25
著者
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坂本 正徳
Meiji College of Pharmacy
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簡 俊生
Meiji College of Pharmacy
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川崎 知巳
明治薬科大学
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高波 利克
Meiji College Of Pharmacy
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川崎 知巳
Meiji College of Pharmacy
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