Alka1oids of Corydalis incisa PERS. II. The Structure of Corydalic Acid Methyl Ester^<2)>
スポンサーリンク
概要
- 論文の詳細を見る
The structure (I) of a new alkaloid, corydalic acid methyl ester, mp 140-141°, [α]_D+85.4°, C_<22>H_<23>O_6N, isolated from Corydalis incisa PERS. (Papaveraceae) only in the vegetative stage, was established by the spectroscopic studies and chemical correlation with mesotetrahydrocorysamine. Furthermore, on the basis of the stereochemical investigation of mesotetrahydrocorysamine, the stereostructure of corydalic acid methyl ester was determined as XII. Corydalic acid methyl ester is a noteworthy natural alkaloid in which aromatic ring is attached to the position-3 of the tetrahydroisoquinoline, and biogenetically it is supposed to be derived from protoberberine skeleton by a fission of B-ring, possibly through an aldehyde-type intermediate.
- 公益社団法人日本薬学会の論文
- 1973-05-25
著者
-
野中 源一郎
Faculty of Pharmaceutical Sciences, Kyushu University 62
-
西岡 五夫
Faculty Of Pharmaceutical Sciences Kyushu University
-
小寺 喜子
Faculty Of Pharmaceutical Sciences Kyushu University
関連論文
- Tannins and Related Compounds. CXXIV. Five New Ellagitannins, Platycaryanins A, B, C, and D, and Platycariin, and a New Complex Tannin, Strobilanin, from the Fruits and Bark of Platycarya strobilacea SIEB et ZUCC., and Biomimetic Synthesis of C-Glycosidic
- Tannins and Related Compounds. CXXIV. Five New Ellagitannins, Platycaryanins A, B, C, and D, and Platycariin, and a New Complex Tannin, Strobilanin, from the Fruits and Bark of Platycarya strobilacea SIEB et ZUCC., and Biomimetic Synthesis of C-Glycosidic
- Inhibitory Effects of Tannins on NADH Dehydrogenases of Various Organisms
- Tannins and Related Compounds. CXXIII. Chromone, Acetophenone and Phenylpropanoid Glycosides and Their Galloyl and/or Hexahydroxydiphenoyl Esters from the Leaves of Syzygium aromaticum MERR. et PERRY
- Tannins and Related Compounds. CXXIII. Chromone, Acetophenone and Phenylpropanoid Glycosides and Their Galloyl and/or Hexahydroxydiphenoyl Esters from the Leaves of Syzygium aromaticum MERR. et PERRY
- Tannins and Related Compounds. CXXII. New Dimeric, Trimeric and Tetrameric Ellagitannins, Lambertianins A-D, from Rubus lambertianus SERINGE
- Tannins and Related Compounds. CXVII. Isolation and Characterization of Three New Ellagitannins, Lagerstannins A, B and C, Having a Gluconic Acid Core, from Lagerstroemia speciosa (L.) PERS
- Tannins and Related Compounds. CXVIII. Structures, Preparation, High-Performance Liquid Chromatography and Some Reactions of Dehydroellagitannin-Acetone Condensates
- Tannins and Related Compounds. CXIX. Samarangenins A and B, Novel Proanthocyanidins with Doubly Bonded Structures, from Syzygium samarangens and S. aqueum
- Tannins and Related Compounds. CXVI. Six New Complex Tannins, Guajavins, Psidinins and Psiguavin from the Bark of Psidium guajava L.
- Tannins and Related Compounds. CXIV. Structure of Novel Fermentation Products, Theogallinin, Theaflavonin and Desgalloyl Theaflavonin from Black Tea, and Changes of Tea Leaf Polyphenols during Fermentation
- Tannins and Related Compounds. CVIII. Isolation and Characterization of Novel Complex Tannins (Flavono-ellagitannins), Anogeissinin and Anogeissusins A and B, from Anogeissus acuminata (ROXB ex DC.) GUILL. et PERR. var. lanceolata WALL. ex CLARKE
- Tannins and Related Compounds. CIX. Isolation of Alienanins A and B, Novel C, C-Linked Ellagitannin Dimers from Quercus aliena BLUME
- Potentiating Effect of Converting Enzyme Inhibitor Captopril to the Renal Responses of Magnesium Lithospermate B in Rats with Adenine-Induced Renal Failure
- Potentiating Effect of Converting Enzyme Inhibitor Captopril to the Renal Responses of Magnesium Lithospermate B in Rats with Adenine-Induced Renal Failure
- Tannins and Related Compounds. CVII. Structure Elucidation of Three New Monomeric and Dimeric Ellagitannins, Flosin B and Reginins C and D, Isolated from Lagerstroemia flos-reginae RETZ.
- Tannins and Related Compounds. CVI. Preparation of Aminoalditol Derivatives of Hydrolyzable Tannins Having α-and β-Glucopyranose Cores, and Its Application to the Structure Elucidation of New Tannins, Reginins A and B and Flosin A, Isolated from Lagerstro
- Tannins and Related Compounds. CVI. Preparation of Aminoalditol Derivatives of Hydrolyzable Tannins Having α-and β-Glucopyranose Cores, and Its Application to the Structure Elucidation of New Tannins, Reginins A and B and Flosin A, Isolated from Lagerstro
- Inhibitory Effects of Tannins on Hyaluronidase Activation and on the Degranulation from Rat Mesentery Mast Cells
- Tannins and Related Compounds. CV. Monomeric and Dimeric Hydrolyzable Tannins Having a Dehydrohyxahydroxydiphenoyl Group, Supinanin, Euphorscopin, Euphorhelin and Jolkianin, from Euphorbia Species
- Tannins and Related Compounds. CIII. Isolation and Characterizatino of New Monomeric, Dimeric and Trimeric Ellagitannins, Calamansanin and Calamanins A, B and C, from Terminalia calamansanai (BLANCO) ROLFE
- Tannins and Related Compounds. C. : Reaction of Dehydrohexahydroxydiphenic Acid Esters with Bases, and Its Application to the Structure Determination of Pomegranate Tannins, Granatins A and B
- Tannins and Related Compounds. XCVIII. : Structures of Three New Dimeric Ellagitannins, Excoecarianin and Excoecarinins A and B, Isolated from the Leaves of Excoecaria kawakamii HAYATA
- Tannins and Related Compounds. XCVII. : Structure Revision of C-Glycosidic Ellagitannins, Castalagin, Vescalagin, Casuarinin and Stachyurin, and Related Hydrolyzable Tannins
- Tannins and Related Compounds. XCVI. : Structures of Macaranins and Macarinins, New Hydrolyzable Tannins Possessing Macaranoyl and Tergalloy Ester Groups, from the Leaves of Macaranga sinensis (BAILL.) MUELL.-ARG.
- Tannins and Related Compounds. XCV. : Isolation and Characterization of Helioscopinins and Helioscopins, Four New Hydrolyzable Tannins from Euphorbia helioscopia L. (1)
- Tannins and Related Compounds. XCII. : Isolation and Characterization of Cyanogenic Ellagitannins, Aleurinins A and B, and a Related O-Glycosidic Ellagitannin, Aleurinin C, from Aleurites fordii HEMSLEY
- Effect of Magnesium Lithospermate B on Urinary Excretion of Arachidonate Metabolites in Rats with Renal Failure
- Tannins and Related Compounds. LXXIX. Isolation and Characterization of Novel Dimeric and Trimeric Hydrolyzable Tannins, Nuphrins C, D, E and F, from Nuphar japonicum DC.
- Contribution of Prostaglandins to the Renal Responses to Magnesium Lithospermate B Isolated from Salviae Miltiorrhizae Radix
- Magnesium and Ammonium-Potassium Lithospermates B, the Active Principles Having a Uremia-Preventive Effect from Salvia miltiorrhiza
- Tannins and Related Compounds. LXXV. : Isolation and Characterization of Novel Diastereoisomeric Ellagitannins, Nupharins A and B, and Their Homologues from Nuphar japonicum DC.
- Tannins and Related Compounds. XLII. : Isolation and Characterization of Four New Hydrolyzable Tannins, Terflavins A and B, Tergallagin and Tercatain from the Leaves of Terminalia catappa L.
- Tannins and Related Compounds. XLI. : Isolation and Characterization of Novel Ellagitannins, Punicacorteins A, B, C, and D, and Punigluconin from the Bark of Punica granatum L.
- Tannins and Related Compounds. XL. : Revision of the Structures of Punicalin and Punicalagin, and Isolation and Characterization of 2-O-Galloylpunicalin from the Bark of Punica granatum L.
- Tannins and Related Compounds. XXI. Isolation and Characterization of Galloyl and p-Hydroxybenzoyl Esters of Benzophenone and Xanthone C-Glucosides from Mangifera indica L.
- Tannins and Related Compounds. XVII. Galloylhamameloses from Castanea crenata L. and Sanguisorba officinalis L.
- Tannins and Related Compounds. XVI. Isolation and Characterization of Six Methyl Glucoside Gallates and a Gallic Acid Glucoside Gallate from Sanguisorba officinalis L.
- A DIMERIC HYDROLYZABLE TANNIN, SANGUIIN H-6 FROM SANGUISORBA OFFICINALIS L.
- Tannins and Related Compounds. XC. : 8-C-Ascorbyl (-)-Epigallocatechin 3-O-Gallate and Novel Dimeric Flavan -3-ols, Oolonghomobisflavans A and B, from Oolong Tea. (3)
- Tannins and Related Compounds. LXXVII. : Novel Chalcan-flavan Dimers, Assamicains A, B and C, and a New Flavan-3-ol and Proanthocyanidins from the Fresh Leaves of Camella sinensis L. var. assamica KITAMURA
- Tannins and Related Compounds. LXIX. : Isolation and Structure Elucidation of B, B'-Linked Bisflavanoids, Theasinensins D-G and Oolongtheanin from Oolong Tea. (2)
- Tannins and Related Compounds. LVI. Isolation of Four New Acylated Flavan-3-ols from Oolong Tea. (1)(Organic,Chemical)
- Tannins and Related Compouns. XXXVI. : Isolation and Structures of Theaflagallins, New Red Pigments from Black Tea
- Mechanism of the Blood Urea Nitrogen-decreasing Activity of Rhatannin from Rhei Rhizoma in the Rat. I
- Effect of Extract from Paeoniae Radix on Urea-nitrogen Concentration in Rat Serum. I
- Effect of Rhatannin on Glutamine Metabolism in Rat Liver
- Effect of Rhatannin on the Incorporation of Precursors into Proteins and Ribonucleic Acids of Rat Liver
- Mechanism of Action of Rhatannin on Plasma Amino Acid Levels in Rats
- Tannins and Related Compounds. XII. Isolation and Characterization of Galloylglucoses from Paeoniae Radix and Their Effect on Urea-Nitrogen Concentration in Rat Serum
- Tannins and Related Compounds. LXXVI. : Isolation and Characterization of Cercidinins A and B and Cuspinin, Unusual 2,3-(R)-Hexahydroxydiphenoyl Glucoses from Cercidiphyllum japonicum and Castanopsis cuspidata var. sieboldii
- Tannins and Related Compounds. LXVII. : Isolation and Characterization of Castanopsinins A-H, Novel Ellagitannins Containing a Triterpenoid Glycoside Core, from Castanopsis cuspidata var. sieboldii NAKAI. (3)
- Tannins and Related Compounds. LXIV. : Six New Phenol Glucoside Gallates from Castanopsis cuspidata var. sieboldii NAKAI. (2)
- Tannins and Related Compounds. LXIII. : Isolation and Characterization of Mongolicains A and B, Novel Tannins from Quercus and Castanopsis Species
- Tannins and Related Compounds. XXV. A New Class of Gallotannins Possessing a (-)-Shikimic Acid Core from Castanopsis cuspidata var. sieboldii NAKAI. (1)
- Tannins and Related Compounds. LXXXV. : Structures of Novel C-Glycosidic Ellagitannins, Grandinin and Pterocarinins A and B
- Studies on Rhubarb (Rhei Rhizoma). XIV. : Isolation and Characterization of Stilbene Glucosides from Chinese Rhubarb
- NOVEL HYDROLYZABLE TANNINS FROM NUPHAR JAPONICUM DC.
- Structure of Gallotannins in Paeoniae Radix
- Tannins and Related Compounds. LXXII. : Isolation and Characterization of Mongolicanin (Procyanidino-ellagitannin), Mongolinin A, Acutissimin C and Vescalagin Carboxylic Acid, Novel Tannins from Quercus mongolica var. grosseserrata
- Tannins and Related Compounds. LXXI. : Isolation and Characterization of Mongolicins A and B, Novel Flavono-ellagitannins from Quercus mongolica var. grosseserrata
- Tannins and Related Compounds. XXXI. Isolation and Characterization of Proanthocyanidins in Kandelia candel (L.) DRUCE
- Inhibitors of Angiotensin-Converting Enzyme in Crude Drugs. II
- Tannins and Related Compounds. LII. : Studies on the Constituents of the Leaves of Thujopsis dolabrata SIEB. et ZUCC.(Pharmacognosy,Chemical)
- Tannins and Related Compounds. XCIII. : Occurrence of Enantiomeric Proanthocyanidins in the Leguminosae Plants, Cassia fistula L. and C. javanica L.
- Tannins and Related Compounds. CII. : Structures of Terchebulin, an Ellagitannin Having a Novel Tetraphenylcarboxylic Acid(Terchebulic Acid)Moiety, and Biogenetically Related Tannins from Terminalia chebula RETZ.
- Studies on Xanthoxylum spp. II. Constituents of the Bark of Xanthoxylum piperitum DC.
- Four New Lignans, Xanthoxylol, Piperitol and Their γ, γ-Dimethylallyl Ethers, from Xanthoxylum piperitum Bark
- Tannins and Related Compounds. XXXIII. Isolation and Characterization of Procyanidins in Dioscorea cirrhosa LOUR.
- Tannins and Related Compounds.XCI. : Isolation and Characterization of Proanthocyanidins with an Intramolecularly Doubly-Linked Unit from the Fern, Dicranopteris pedata HOUTT.
- Studies on Rhubarb (Rhei Rhizoma). XV. : Simultaneous Determination of Phenolic Constituents by High-Performance Liquid Chromatography
- Tannins and Related Compounds. XLVIII. : Rhubarb. (7). Isolation and Characterization of New Dimeric and Trimeric Procyanidins
- Tannins and Related Compounds. XLVII. : Rhubarb. (6). Isolation and Characterization of New p-Hydroxyphenylbutanones, Stilbenes and Gallic Acid Glucosides
- Tannins and Related Compounds. XLV. Rhubarb. (5). : Isolation and Characterization of Flavan-3-ol and Procyanidin Glucosides
- Studies on Rhubarb (Rhei Rhizoma). VI. Isolation and Characterization of Stilbenes
- Studies on Rhubarb (Rhei Rhizoma). V. Isolation and Characterization of Chromone and Chromanone Derivatives
- Tannins and Related Compounds. XXIII. Rhubarb (4) : Isolation and Structures of New Classes of Gallotannins
- Tannins and Related Compounds. XCIV. : Isolation and Characterization of Seven New Hydrolyzable Tannins from the Leaves of Macaranga tanarius (L.) MUELL. et ARG.
- Tannins and Related Compounds. LXXXVIII. : Isolation and Characterization of Hydrolyzable Tannins from Mallotus japonicus (THUNB.) MUELLER-ARG. and M. philippinensis (LAM.) MUELLER-ARG.
- Tannins and Related Compounds. LXXXVII. : Isolation and Characterization of Four New Hydrolyzable Tannins from the Leaves of Mallotus repandus
- Studies on the components of the Leaves of Coptis japonica MAKINO. I. The Structures of Coptiside I and II
- Tannins and Related Compounds. I. Rhubarb (1)
- Effect of Extracts Obtained from Rhubarb in Rats with Chronic Renal Failure
- Trapain, a New Hydrolyzable Tannin from Trapa Japonica FLEROV.
- Alka1oids of Corydalis incisa PERS. II. The Structure of Corydalic Acid Methyl Ester^
- Tannins and Related Compounds. XLVI. : Isolation and Structures of Stenophynins A and B, Novel Tannins from Quercus stenophylla MAKINO
- Tannins and Related Compounds. XX. Two New Ellagitannins Containing a Proto-quercitol Core from Quercus stenophylla MAKINO. (4)
- Tannins and Related Compounds. XIX. Eight New Gallotannins Containing a Proto-quercitol Core from Quercus stenophylla MAKINO. (3)
- Tannins and Related Compounds. XVIII. A Gallotannin and Two Ellagitannins Containing a p-Hydroxyphenethyl Alcohol 1-O-β-D-Glucoside (Salidroside) Core from Quercus stenophylla MAKINO. (2)
- Tannins and Related Compounds. IV. Seven New Phenol Glucoside Gallates from Quercus stenophylla MAKINO (1)
- Tannins and Related Compounds. LXXXIV. : Isolation and Characterization of Five New Hydrolyzable Tannins from the Bark of Mallotus japonicus
- Tannins and Related Compounds. LXXXIII. : Isolation and Structures of Hydrolyzable Tannins, Phillyraeoidins A-E from Quercus phillyraeoides
- Tannins and Related Compounds. LXI. : Isolation and Structures of Novel Bi- and Triflavanoids from the Leaves of Cassia fistula L.
- Tannins and Related Compounds. LX. : Isolation and Characterization of Proanthocyanidins with a Doubly-Linked Unit from Vaccinium vitis-idaea L.
- Tannins and Related Compounds. LIX. Aesculitannins, Novel Proanthocyanidins with Doubly-Bonded Structures from Aesculus hippocastanum L.(Organic,Chemical)
- Tannins and Related Compounds. LV. Isolation and Characterization of Acutissimins A and B, Novel Tannins from Quercus and Castanea Species(Organic,Chemical)
- Tannins and Related Compounds. LI. Elucidation of the Stereochemistry of the Triphenoyl Moiety in Castalagin and Vescalagin, and Isolation of 1-O-Galloyl Castalagin from Eugenia grandis(Organic,Chemical)
- Tannins and Related Compounds. L. Structures of Proanthocyanidin A-1 and Related Compounds(Organic,Chemical)
- ELAEOCARPUSIN, A PROTO-TYPE OF GERANIIN FROM GERANIUM THUNBERGII
- Tannins and Related Compounds. XXXIX. : Procyanidin C-Glucosides and an Acylated Flavan-3-ol Glucoside from the Barks of Cinnamomum cassia BLUME and C. obtusifolium NEES