Effects of Electron Donors on the Photodecomposition of Menadione in Aqueous Solution. III. The Relation between the Structure of the Complex in Electronic Aspect and the Rate of Stabilization
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概要
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In a previous paper, it was reported that the photodecomposition of menadione in aqueous solution was inhibited by the formation of the complex with various electron donors, and it was suggested that the complex formation among them might be attributed to charge-transfer force. The relationship between the structure of the complex in electronic aspect and the rate of stabilization were investigated by a molecular orbital method described in this paper. As a result, it was concluded that suppression of the photodecomposition of menadione with various electron donors is due to the charge transfer complex formation among them.
- 公益社団法人日本薬学会の論文
- 1968-01-25
著者
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富岡 穂一
Research Laboratory, Chugai Pharmaceutical Co., Ltd.
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畑 俊一
Research Laboratories, Chugai Pharmaceutical Co., Ltd.
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水野 光司
中外製薬新薬研究所
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富岡 穂一
中外製薬株式会社綜合研究所
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水野 光司
Research Laboratories, Chugai Pharmaceutical Co., Ltd., Takada, Toshima-ku, Tokyo
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畑 俊一
Research Laboratories Chugai Pharmaceutical Co. Ltd.
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富岡 穂一
Research Laboratory Chugai Pharmaceutical Co. Ltd.
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水野 光司
Research Laboratories Chugai Pharmaceutical Co. Ltd.
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