Effects of Electron Donors on the Photodecomposition of Menadione in Aqueous Solution. I. The Interaction between Electron Donors and Menadione in Aqueous Solution.
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概要
- 論文の詳細を見る
Among nine pharmaceutical preparations, the values of parameters λ_<h.o.> and λ_<l.e.> representing the energy levels of the highest occupied molecular orbital and the lowest empty molecular orbital were obtained by a molecular orbital method, simple LCAO MO method of π-electrons. On the basis of these calculations, it was found that eight electron donors used formed the molecular complex with menadione in aqueous media. The free energy changes in the complex formation tend to be increased by the addition of better eletron donors. As a result, it was suggested that the driving force of the complex formation would be due to charge transfer force.
- 公益社団法人日本薬学会の論文
- 1967-11-25
著者
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富岡 穂一
Research Laboratory, Chugai Pharmaceutical Co., Ltd.
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畑 俊一
Research Laboratories, Chugai Pharmaceutical Co., Ltd.
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水野 光司
中外製薬新薬研究所
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富岡 穂一
中外製薬株式会社綜合研究所
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水野 光司
Research Laboratories, Chugai Pharmaceutical Co., Ltd., Takada, Toshima-ku, Tokyo
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畑 俊一
Research Laboratories Chugai Pharmaceutical Co. Ltd.
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富岡 穂一
Research Laboratory Chugai Pharmaceutical Co. Ltd.
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水野 光司
Research Laboratories Chugai Pharmaceutical Co. Ltd.
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