Bile Acids and Steroids. XII. Thiosteroids (1). The Fission of Epoxide in the C-Ring of Steroids by Thiocyanic Acid

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概要

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• When steroidal 11α, 12α-, 11β, 12β-, and 9β, 11β-epoxides were each treated with thiocyanic acid, the corresponding thiocyanatohydrins were obtained. The thiocyanato and hydroxyl groups of these ring-fission products were assumed to be trans and diaxial to each other by Barton's generalization, and from infrared and ultraviolet data. This was also confirmed by chemical methods.

• 公益社団法人日本薬学会の論文
• 1960-05-25

著者

• 米野 太一郎

  Research Laboratory, Shionogi & Co., Ltd.

• 武田 健一

  Research Laboratory Shionogi & Co. Ltd.

• Takeda Ken'ichi

  Shionogi Research Laboratory Shionogi & Co. Ltd.

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